Interfacial influence on mechanical properties of polypropylene/polypropylene-grafted silica nanocomposites

被引:0
作者
Wang, Wei [1 ]
Wu, Jingshen [1 ]
机构
[1] Hong Kong Univ Sci & Technol, Dept Mech & Aerosp Engn, Kowloon, Hong Kong, Peoples R China
关键词
mechanical properties; polyolefins; surfaces and interfaces; DRUG-DELIVERY; CARBON-STEEL; CORROSION-INHIBITORS; PHOSPHATE IONS; PH; HYDROGELS; CONCRETE; POLYMER; REINFORCEMENT; PERFORMANCE;
D O I
10.1002/APP.45887
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Three types of polypropylene-grafted silica (PGS-2 K, PGS-8 K and PGS-30 K) with different grafting chain lengths were prepared. After melt-blending PGS with polypropylene (PP), we studied the PP/PGS interface properties and the influence of PP/PGS interfaces on mechanical properties of nanocomposites. The strong matrix/particle interface was observed in PP/PGS-30 K nanocomposites with 5 wt % particle loading as evidenced by 2.5 degrees C increased glass transition temperature (T-g) compared with neat PP, whereas the weak matrix/particle interface was observed in PP/PGS-2 K nanocomposites with decreased T-g. The variations in the matrix/particle interfacial strength lead to a transition in the yield stress of nanocomposites. Compared with the unfilled PP, the yield stress of the PP/PGS-2 K nanocomposites is decreased by 0.7 MPa, and the yield stress of the PP/PGS-30 K nanocomposites is enhanced by 1.4 MPa. In addition, benefiting from good dispersion, the PP/PGS-masterbatch nanocomposites with a strong matrix/particle interface not only exhibit increased Young's modulus and yield stress, but also the strain at break remains in line with the unfilled PP, which is in contrast to the conventional wisdom that the gain in modulus and strength must be at the expense of the decreased break strain. (C) 2017 Wiley Periodicals, Inc.
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页数:10
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