2,2′-[1,5-Bis(4-aminophenyl)-1,5-dihydrobenzo[1,2-d;4,5-d′]diimidazole-2,6-diyl]diphenol

被引：1

作者：

Blagus, Anita ^{[1
]}

Kaitner, Branko ^{[2
]}

机构：

[1] JJ Strossmayer Univ, Dept Chem, HR-31000 Osijek, Croatia

[2] Univ Zagreb, Fac Sci, Dept Chem, Lab Gen & Inorgan Chem, HR-10002 Zagreb, Croatia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

data-to-parameter ratio = 14.2; mean σ(C-C) = 0.003 Å; R factor = 0.053; single-crystal X-ray study; T = 298 K; wR factor = 0.123;

D O I：

10.1107/S1600536811036737

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title molecule, C32H24N6O2, has a crystallographic inversion centre in the middle of the benzodiimidazole core. It exists as the enol-imine tautomeric form and exhibits a strong intramolecular O-H center dot center dot center dot N hydrogen bond. The dihedral angles between the planes of the 2-hydroxyphenyl and 4-aminophenyl substituents and the plane of the benzodiimidazole unit [12.69 (8) and 84.71 (8)degrees, respectively] differ significantly due to steric reasons. In the crystal, molecules are linked by C-H center dot center dot center dot pi interactions, forming a two-dimensional network.

引用

页码：O2666 / +

页数：12

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