Synthesis of gem-dihydroperoxides from ketones using silica-supported sodium hydrogen sulfate as a heterogeneous catalyst

被引：49

作者：

Das, Biswanath ^{[1
]}

Veeranjaneyulu, Boyapati ^{[1
]}

Krishnaiah, Maddeboina ^{[1
]}

Balasubramanyam, P. ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Chem Div 1, Hyderabad 500007, Andhra Pradesh, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2008年 / 284卷 / 1-2期

关键词：

NaHSO(4)center dot SiO(2); ketones; gem-dihydroperoxides; heterogeneous catalyst;

D O I：

10.1016/j.molcata.2008.01.016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

NaHSO(4)center dot SiO(2) was found to be an efficient catalyst for the synthesis of gem-dihydroperoxides from ketones and aqueous (50%) H(2)O(2) under mild and heterogeneous conditions at room temperature within a short period of time. The method presented here has the advantages of environmental benignancy, good to excellent yields and simple operational procedure. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：116 / 119

页数：4

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