Macromolecular design and application using Mn2(CO)10-based visible light photoinitiating systems

被引：39
|
作者：
Ciftci, Mustafa [1 ]
Tasdelen, Mehmet Atilla [2 ]
Yagci, Yusuf [1 ,3 ,4 ]
机构：
[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey
[2] Yalova Univ, Dept Polymer Engn, Fac Engn, TR-77100 Yalova, Turkey
[3] King Abdulaziz Univ, CEAMR, Fac Sci, POB 80203, Jeddah 21589, Saudi Arabia
[4] King Abdulaziz Univ, Dept Chem, Fac Sci, POB 80203, Jeddah 21589, Saudi Arabia
来源：
POLYMER INTERNATIONAL | 2016年 / 65卷 / 09期
关键词：
metal carbonyls; metal-organic catalysts; photopolymerization; polymer synthesis; radical polymerization; FREE-RADICAL POLYMERIZATION; PROMOTED CATIONIC-POLYMERIZATION; TRANSITION-METAL CARBONYLS; PHOTO-INITIATING SYSTEMS; AZO-BENZOIN INITIATORS; MANGANESE CARBONYL; BLOCK-COPOLYMERS; METHYL ACRYLATE; DIMANGANESE DECACARBONYL; VINYL POLYMERIZATION;
D O I：
10.1002/pi.5111
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The environmentally friendly Mn-2(CO)(10)-based visible light photoinitiating system is a powerful method for the preparation of linear and crosslinked polymeric structures. From a practical point of view, the most important feature of this initiating system is its optical characteristics in the visible range with high quantum yield and good solubility properties. This photoinitiating system is applicable for a variety of monomers that can be polymerized via either radical or cationic mechanisms. Various complex macromolecular structures such as telechelic polymers, block and graft copolymers, polymer networks and surface modifications can be simply prepared by using halogenated precursors. This photoinitiating system is also combined with controlled radical polymerization techniques providing a mild and efficient method for polymer synthesis. (c) 2016 Society of Chemical Industry
引用
收藏
页码：1001 / 1014
页数：14
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