Mechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex

被引：42

作者：

Huffman, Lauren M. ^{[1
]}

Stahl, Shannon S. ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

DALTON TRANSACTIONS | 2011年 / 40卷 / 35期

关键词：

COPPER; SELECTIVITIES; ARYLATION;

D O I：

10.1039/c1dt10463b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A net trans C-N reductive elimination reaction is observed from a macrocyclic aryl-Cu-III complex, and a mechanistic study of this reaction indicates that coordinating ligands play a role in mediating this unusual transformation.

引用

页码：8959 / 8963

页数：5

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