Solvent-free selective oxidation of primary alcohols-to-aldehydes and aldehydes-to-carboxylic acids by molecular oxygen over MgO-supported nano-gold catalyst

被引：53

作者：

Choudhary, Vasant R. ^{[1
]}

Dumbre, Deepa K. ^{[1
]}

机构：

[1] Natl Chem Lab, Chem Engn & Proc Dev Div, Pune 411008, Maharashtra, India

来源：

CATALYSIS COMMUNICATIONS | 2011年 / 13卷 / 01期

关键词：

Alcohols; Aldehydes; Au/MgO; Molecular oxygen; Solvent-free oxidation; TERT-BUTYL HYDROPEROXIDE; BENZYL ALCOHOL; TRANSITION-METAL; AL HYDROTALCITE; BENZALDEHYDE; PD; EPOXIDATION; STYRENE; NICKEL;

D O I：

10.1016/j.catcom.2011.07.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Magnesium oxide supported nano-gold catalyst (prepared by the homogeneous deposition precipitation technique) showed high activity/selectivity and excellent reusability in the oxidation of different primary alcohols and aldehydes to corresponding aldehydes and carboxylic acids, respectively, by molecular oxygen (under atmospheric pressure) in the absence of any solvent. Influence of the catalyst calcination temperature (400-900 degrees C), reaction temperature (50-120 degrees C) and use of different solvents (viz. toluene. p-xylene, DMF or DMSO) on the oxidation reaction has also been studied. (C) 2011 Published by Elsevier B.V.

引用

页码：82 / 86

页数：5

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