Investigation of pure and g-C3N4 loaded CdWO4 photocatalytic activity on reducing toxic pollutants

被引:17
作者
Keerthana, S. P. [1 ]
Yuvakkumar, R. [1 ]
Kumar, P. Senthil [2 ,3 ]
Ravi, G. [1 ]
Hong, S., I [4 ]
Velauthapillai, Dhayalan [5 ]
机构
[1] Alagappa Univ, Dept Phys, Karaikkudi 630003, Tamil Nadu, India
[2] Sri Sivasubramaniya Nadar Coll Engn, Dept Chem Engn, Chennai 603110, Tamil Nadu, India
[3] Sri Sivasubramaniya Nadar Coll Engn, Ctr Excellence Water Res CE War, Chennai 603110, Tamil Nadu, India
[4] Chungnarn Natl Univ, Dept Mat Sci & Engn, Daejeon, South Korea
[5] Western Norway Univ Appl Sci, Fac Engn & Sci, N-5063 Bergen, Norway
关键词
CdWO; 4; G-C; 3; N; 4-CdWO; PEG; MB dye; GRAPHITIC CARBON NITRIDE; WASTE-WATER; DEGRADATION; PERFORMANCE; TUNGSTATE; HETEROSTRUCTURE; FABRICATION; NANORODS; BI2WO6; DYES;
D O I
10.1016/j.chemosphere.2021.133090
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A facile synthesis of pristine and g-C3N4 loaded CdWO4 (Cadmium Tungstate) were reported and analyzed the effect of pollutants removal in wastewater. The samples were characterized and the morphology of the pristine sample showed the nanostructures with high cluster of layer formed. While adding PEG (Polyethylene glycol), the surface has exhibited less agglomeration and in g-C3N4 added sample the agglomeration was intensely reduced and nanostructures have been clearly found. Photocatalytic performance on cationic dye was investigated under visible light. The efficiency calculated for g-C3N4- CdWO4 sample was 85% for MB. The C/C0 plot gives better degradation. The kinetic study revealed pseudo first order reaction. The g-C3N4-CdWO4 sample exhibited higher "k" value which proved best efficiency on removing the pollutant. g-C3N4-CdWO4 sample will make better reduction on toxic pollutants and be a good candidate in futuristic applications. By carbon based derivates inclusion with photo active materials, the morphology and surface area was greatly improved and it enhances activity of host material and it will be the promising material for industrial applications.
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页数:10
相关论文
共 62 条
[1]   Praseodymium-doped cadmium tungstate (CdWO4) nanoparticles for dye degradation with sonocatalytic process [J].
Ahmadi, Shahin ;
Rahdar, Abbas ;
Igwegbe, Chinenye Adaobi ;
Mortazavi-Derazkola, Sobhan ;
Banach, Artur Marek ;
Rahdar, Somayeh ;
Singh, Ajaya Kumar ;
Rodriguez-Couto, Susana ;
Kyzas, George Z. .
POLYHEDRON, 2020, 190 (190)
[2]   Influence of PVA, PVP and PEG doping on the optical, structural, morphological and magnetic properties of zinc ferrite nanoparticles produced by thermal method [J].
Aisida, Samson O. ;
Akpa, Paul A. ;
Ahmaed, Ishaq ;
Maaza, M. ;
Ezema, Fabian, I .
PHYSICA B-CONDENSED MATTER, 2019, 571 :130-136
[3]   Application of heterogeneous nano-semiconductors for photocatalytic advanced oxidation of organic compounds: A review [J].
Akerdi, Abdollah Gholami ;
Bahrami, S. Hajir .
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2019, 7 (05)
[4]   A review on hybrid techniques for the degradation of organic pollutants in aqueous environment [J].
Anandan, Sambandam ;
Ponnusamy, Vinoth Kumar ;
Ashokkumar, Muthupandian .
ULTRASONICS SONOCHEMISTRY, 2020, 67
[5]  
Aslam Imran, 2019, Materials Science for Energy Technologies, V2, P401, DOI 10.1016/j.mset.2019.04.008
[6]   Influence of g-C3N4 and g-C3N4 nanosheets supported CuS coupled system with effect of pH on the catalytic activity of 4-NP reduction using NaBH4 [J].
Ayodhya, Dasari ;
Veerabhadram, Guttena .
FLATCHEM, 2019, 14
[7]   An efficient photocatalyst for degradation of various organic dyes: Ag@Ag2MoO4-AgBr composite [J].
Bai, Yu-Yang ;
Lu, Yi ;
Liu, Jin-Ku .
JOURNAL OF HAZARDOUS MATERIALS, 2016, 307 :26-35
[8]   Fractionation of UV and VUV pretreated natural organic matter from drinking water [J].
Buchanan, W ;
Roddick, F ;
Porter, N ;
Drikas, M .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (12) :4647-4654
[9]  
Chaudhry, 2019, WATER RESOUR IND, V22, P100119, DOI [10.1016/j.wri.2019.100119, DOI 10.1016/J.WRI.2019.100119]
[10]   Three-dimension hierarchical heterostructure of CdWO4 microrods decorated with Bi2WO6 nanoplates for high-selectivity photocatalytic benzene hydroxylation to phenol [J].
Chen, Peng ;
Chen, Lang ;
Zeng, Yu ;
Ding, Feng ;
Jiang, Xu ;
Liu, Na ;
Au, Chak-Tong ;
Yin, Shuang-Feng .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 234 :311-317