Synthesis of Z-alkenes via visible light promoted photocatalytic E → Z isomerization under metal-free conditions

被引：71

作者：

Cai, Wenbin ^{[1
]}

Fan, Huaqiang ^{[1
]}

Ding, Dazhong ^{[2
]}

Zhang, Yongqiang ^{[1
]}

Wang, Wei ^{[1
,3
]}

机构：

[1] East China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China

[2] Qingdao Inst Food & Drug Control, Qingdao 266000, Peoples R China

[3] Univ New Mexico, Dept Chem & Chem Biol, Albuquerque, NM 87131 USA

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 96期

关键词：

PHOTOCHEMICAL-REACTIONS; ENERGY-TRANSFER; MECHANISMS; OLEFIN; METATHESIS; ACTIVATION; CATALYSTS; RING;

D O I：

10.1039/c7cc07984b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A green approach for the synthesis of thermodynamically less stable Z-alkenes has been presented through the exploration of visible light promoted photocatalytic E-to-Z isomerization. This protocol features metal-free conditions, which is operationally simple, remarkably clean, and allows the synthesis of both electron-rich and electron-deficient Z-alkenes with diverse functional groups.

引用

页码：12918 / 12921

页数：4