A 2D Zn(II) coordination polymer constructed by right-handed and left-handed Zn-Hbci-Zn helical chains and μ2-H2O bridges (H3bci = bis(2-carboxyethyl)isocyanurate)

被引：4
作者：
Liang, Yan-Fang [2 ]
Wang, Xiao-Fang [1 ]
Zhang, Guo-xin [2 ]
Han, Zheng-Bo [2 ]
机构：
[1] Liaoning Univ, Pharmaceut Coll, Shenyang 110036, Peoples R China
[2] Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 07期
关键词：
Coordination polymer; Helical chains; mu(2)-H2O bridges; Photoluminescence properties; METAL-ORGANIC FRAMEWORKS; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES; COMPLEXES; LIGAND; CLUSTER;
D O I：
10.1016/j.inoche.2011.03.072
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of Zn(OAc)(2)center dot 2H(2)O and bis(2-carboxyethyl)isocyanurate (H(3)bci) leads to the generation of a new coordination polymer, Zn(Hbci)(H2O)(3) (1), (H(3)bci=bis(2-carboxyethyl)isocyanurate), which features an interesting 2D layer containing Zn(II)-Hbci-Zn(II) right-handed and left-handed helical chains and mu(2)-H2O bridges. Furthermore, hydrogen bonds link the adjacent 2D layers to form a 3D supramolecular framework. The photoluminescence property of 1 was also studied. Crown Copyright (C) 2011 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：1107 / 1110
页数：4
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