Vaporization Thermodynamics of Pyrrolidinium, Pyridinium, and Imidazolium-Based Ionic Liquids Bearing the Bis(fluorosulfonyl)imide [FSI] and the Bis(trifluoromethylsulfonyl)imide [NTf2] Anions

被引：2
作者：
Zaitsau, Dzmitry H. [1 ,2 ]
Verevkin, Sergey P. [1 ,2 ]
机构：
[1] Univ Rostock, Dept Phys Chem, D-18059 Rostock, Germany
[2] Univ Rostock, Fac Interdisciplinary Res, Competence Ctr CALOR, D-18059 Rostock, Germany
来源：
INTERNATIONAL JOURNAL OF THERMOPHYSICS | 2022年 / 43卷 / 02期
关键词：
Enthalpy of vaporization; Ionic liquid; Vapor pressure; STRUCTURE-PROPERTY RELATIONSHIPS; ENTHALPIES; SIMULATION; ILS;
D O I：
10.1007/s10765-021-02946-2
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
New experimental vapor pressures in the range 407 K to 460 K and vaporization enthalpy of the ionic liquids (IL) N-alkyl-N-methyl-pyrrolidinium bis(fluorosulfonyl)imide ionic liquids have been measured using quartz crystal microbalance. The absolute vapor pressures and vaporization enthalpies were compared with analogous pyrrolidinium-based ILs with the bis(trifluoromethanesulfonyl)imide anion. The evaluated difference in vaporization enthalpy of ILs with bis(fluorosulfonyl)imide and bis(trifluoromethanesulfonyl)imide anions allowed for estimation of corresponding property for a wide set of ILs with bis(fluorosulfonyl)imide anion. The results are relevant to chemical engineering calculations of processes involving ILs as reaction and separation media.
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页数：9
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