19F NMR of linear N,N-difluoroaminoalkanes

被引：8

作者：

Belter, Randolph K. ^{[1
]}

机构：

[1] Y Not Chem Consulting, Zachary, LA 70791 USA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2012年 / 137卷

关键词：

N; N-difluoroaminoalkanes; Difluoroalkylamines; F-19; NMR; Nuclear magnetic resonance;

D O I：

10.1016/j.jfluchem.2012.02.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Whereas most N,N-difluoroaminoalkanes exhibit a single F-19 resonance at about +50 ppm, the tri-component mixtures of both N,N-difluoroaminopentanes and N,N-difluoroaminohexanes exhibited a more complex pattern. The individual 1-N,N-difluoroamino-, 2-N,N-difluoroamino- and 3-N,N-difluoroaminopentanes have been synthesized and their separated resonances are reported. (c) 2012 Elsevier B.V. All rights reserved.

引用

页码：73 / 76

页数：4

共 5 条

[1]

Banks RE, 1970, FLUOROCARBONS THEIR, P232

[2] Difluoroalkylamines from high temperature vapor phase reactions of nitrogen trifluoride with alkanes, ethers and benzene [J].