Coordination chemistry of the hexavacant tungstophosphate [H2P2W12O48]12-:: synthesis and characterization of iron(III) complexes derived from the unprecedented {P2W14O54} fragment

被引:62
作者
Godin, B [1 ]
Vaissermann, J [1 ]
Herson, P [1 ]
Ruhlmann, L [1 ]
Verdaguer, M [1 ]
Gouzerh, P [1 ]
机构
[1] Univ Paris 06, Lab Chim Inorgan & Mat Mol, UMR 7071, CNRS,Inst Chim Mol, F-75252 Paris, France
关键词
D O I
10.1039/b510434c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Clusters which display the rare cubic Fe-8 topology have been obtained by reaction of the metastable hexavacant polyoxotungstate [H2P2W12O48](12-) with basic trinuclear metal acetates.
引用
收藏
页码:5624 / 5626
页数:3
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