Copper-Catalyzed Cycloisomerizations of Enynols and Their Esters

被引：26
作者：
Fehr, Charles [1 ]
机构：
[1] Firmenich Co, Corp R&D Div, CH-1211 Geneva 8, Switzerland
来源：
SYNLETT | 2012年 / 07期
关键词：
copper catalysis; cycloisomerizations; fragrances; alkynes; gold catalysis; HOMOGENEOUS GOLD CATALYSIS; FACE-SELECTIVE PLATINUM; ENT-BETA-SANTALENE; PTCL2-MEDIATED CYCLOISOMERIZATION; STEREOSELECTIVE-SYNTHESIS; STEREOSPECIFIC SYNTHESIS; PROPARGYLIC ESTERS; MECHANISTIC INSIGHTS; EFFICIENT SYNTHESIS; CHIRALITY TRANSFER;
D O I：
10.1055/s-0031-1290657
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We have discovered that several platinum-or gold-catalyzed cycloisomerization reactions can also be catalyzed by copper. This Account discusses our new findings, the complementarity of copper-catalysis, and its application to the synthesis of (-)-cubebol, (-)-beta-santalol, and other fragrance compounds.
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页码：990 / 1006
页数：17
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