Ferrimagnetic-like ordering in a unique three-dimensional coordination polymer featuring mixed azide/carboxylate-bridged trinuclear manganese(II) clusters as subunits

被引:137
作者
Chen, HJ
Mao, ZW
Gao, S [1 ]
Chen, XM
机构
[1] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
[2] Jinan Univ, Dept Chem, Guangzhou 510632, Peoples R China
[3] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
关键词
D O I
10.1039/b106314f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structure of the coordination polymer [Mn-3(N-3)(2)(nta)(4)(H2O)(2)] n (nta = nicotinate) consists of trinuclear subunits bridged by mixed mu -1,1-azide and mu -carboxylate-O, O groups, which are linked by mu (3)-nta-N, O, O ligands into a three-dimensional network exhibiting ferrimagnetic-like ordering.
引用
收藏
页码:2320 / 2321
页数:2
相关论文
共 21 条
[1]   A LINEAR POLYMERIC COPPER(II) COMPLEX BRIDGED SIMULTANEOUSLY BY AZIDO, NITRATO, AND BETAINE LIGANDS - CRYSTAL-STRUCTURE OF CATENA-[BIS(MU-(1,1)-AZIDO)BIS(MU-NITRATO-O,O')BIS-((MU-TRIMETHYLAMMONIO)ACETATO-O,O')DICOPPER(II)], [CU2(N3)2(NO3)2(ME3NCH2CO2)2]N [J].
CHOW, MY ;
ZHOU, ZY ;
MAK, TCW .
INORGANIC CHEMISTRY, 1992, 31 (23) :4900-4902
[2]   Influence of pseudohalide ions on the molecular structure and magnetic properties of the manganese(II)-bipyrimidine-pseudohalide system [J].
Cortes, R ;
Urtiaga, MK ;
Lezama, L ;
Pizarro, JL ;
Arriortua, MI ;
Rojo, T .
INORGANIC CHEMISTRY, 1997, 36 (22) :5016-5021
[3]   Synthesis and structural characterization of [Mn(ethyl isonicotinate)(2)(N-3)(2)](n), a two-dimensional alternating ferromagnetic-antiferromagnetic compound. Magnetostructural correlations for the end-to-end pseudohalide-manganese system [J].
Escuer, A ;
Vicente, R ;
Goher, MAS ;
Mautner, FA .
INORGANIC CHEMISTRY, 1996, 35 (22) :6386-6391
[4]   Crystal structure and metamagnetic property of a 2-D layered complex, [FeII(N3)2(pyz)]n (pyz = pyrazine) [J].
Hao, X ;
Wei, YG ;
Zhang, SW .
CHEMICAL COMMUNICATIONS, 2000, (22) :2271-2272
[5]   Novel gallium phosphate framework encapsulating trinuclear Mn3(H2O)6O8 cluster:: Hydrothermal synthesis and characterization of Mn3(H2O)6Ga4(PO4)6 [J].
Hsu, KF ;
Wang, SL .
INORGANIC CHEMISTRY, 2000, 39 (08) :1773-1778
[6]  
Kahn O., 1993, MOL MAGNETISM, P211
[7]   Synthesis and X-ray crystal structure of a novel neutral trinuclear copper(II) hydridotris(3,5-dimethylpyrazolyl)borate complex with 1,1-azido bridges [J].
Lam, MHW ;
Tang, YY ;
Fung, KM ;
You, XZ ;
Wong, WT .
CHEMICAL COMMUNICATIONS, 1997, (10) :957-958
[8]   Linear trinuclear and one-dimensional copper(II) complexes containing co-bridging end-on azido and triazole ligands.: Crystal structures and magnetic properties of [Cu3(atrz)2(N3)6] and [Cu(atrz)2(N3)]NO3 (atrz=4-amino-1,2,4-triazole) [J].
Liu, JC ;
Fu, DG ;
Zhuang, JZ ;
Duan, CY ;
You, XZ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (14) :2337-2342
[9]   MnII(N3)2(pyrazine).: A 2-D layered structure consisting of ferromagnetically coupled 1-D {Mn(μ-1,1-N3)2}n chains [J].
Manson, JL ;
Arif, AM ;
Miller, JS .
CHEMICAL COMMUNICATIONS, 1999, (16) :1479-1480
[10]   [N(CH3)(4)][Mn(N-3)(3)]: A compound with a distorted Perovskite structure through azido ligands [J].
Mautner, FA ;
Cortes, R ;
Lezama, L ;
Rojo, T .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1996, 35 (01) :78-80