Crystal and molecular structure of trans-[IrCl(N2)(PiPr3)2]

被引：5
|
作者：
Boettcher, Hans-Christian [1 ]
Graf, Marion [1 ]
Mayer, Peter [1 ]
Suenkel, Karlheinz [1 ]
机构：
[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2008年 / 634卷 / 08期
关键词：
iridium; phosphane; dinitrogen complex; crystal structure;
D O I：
10.1002/zaac.200800074
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Single crystals of trans-[IrCl(N-2)((PPr3)-Pr-i)(2)] (1), obtained during studies on the reaction of [Ir(mu-Cl)(coe)(2)}(2)] (coe = cis-cyclooctene) with tri-iso-propylphosphane in diethyl ether under dinitrogen atmosphere, have been analyzed by X-ray crystallography (monoclinic, P2(1)/c, Z = 2, a = 8.0855(9), b = 8.896(3), c = 16.539(3) angstrom; beta = 93.124(11)degrees; V = 1187.9(4); T = 200(2) K). In the course of these studies under an atmosphere of dinitrogen or argon, the formation of a variety of phosphorus-containing compounds was indicated using P-31{H-1} NMR spectroscopy.
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页码：1241 / 1243
页数：3
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