Synthesis and Crystal Structure of (Z)-3-Benzyl-5-[4-(benzyloxy)-3-methoxybenzylidene]thiazolidine-2,4-dione

被引：0
|
作者：
Wang, Tingfang [1 ,2 ]
Zheng, Liping [1 ,2 ]
Xiong, Liyan [1 ]
Wang, Jin [1 ]
Zhou, Hao [1 ]
Jin, Lei [1 ]
Zhang, Chuan [1 ]
机构：
[1] Second Mil Med Univ, Sch Pharm, New Drug Res Ctr, Shanghai 200433, Peoples R China
[2] Fujian Univ Tradit Chinese Med, Sch Pharm, Fuzhou 350108, Fujian Province, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2012年 / 24卷 / 02期
关键词：
Synthesis; Crystal structure; (Z)-3-Benzyl-5-(4-(benzyloxy)-3-methoxybenzylidene)thiazolidine-2,4-dione;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis and crystal structure of the (Z)-3-benzyl-5-(4-(benzyloxy)-3-methoxybenzylidene)thiazolidine-2,4-dione has been determined by single crystal X-ray diffraction method. The crystal belongs to triclinic, space group P1, with a = 9.098(4), b = 10585(5), c = 11.609(5)angstrom, alpha = 80.549(6), beta = 88.159(6), gamma = 71.587(4)degrees, V = 1046.2(8)angstrom(3), Z = 2, Dx = 1.370 Mg/m(3), lambda(MoKu) = 0.71073, F(000) = 452, mu(MoK alpha) = 0.188 mm(-1), R = 0.0815 and wR 0.2507 for 2038 reflections with I > 2 sigma(I). The C(6)-C(7) bond (1.506 angstrom) confirm the delocalization of the p electrons between thiazolidine-2,4-dione ring and benzene ring in the title compound, but the thiazolidine-2,4-dione ring and benzene C(7)-C(12) planes are not in the same plane and make a dihedral angle of 16.69(0.20)degrees with each other.
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页码：715 / 717
页数：3
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