Controlled synthesis of uniform ultrafine CuO nanowires as anode material for lithium-ion batteries

被引:68
作者
Wang, Fei [1 ]
Tao, Weizhe [1 ]
Zhao, Mingshu [1 ]
Xu, Minwei [1 ]
Yang, Shengchun [1 ]
Sun, Zhanbo [1 ]
Wang, Liqun [1 ]
Song, Xiaoping [1 ]
机构
[1] Xi An Jiao Tong Univ, Sch Sci, MOE Key Lab Non Equilibrium Synth & Modulat Conde, Xian 710049, Peoples R China
基金
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词
Copper oxide; Ultrafine nanowires; Anode; Lithium-ion battery; ELECTROCHEMICAL PERFORMANCE; ELECTRODE MATERIALS; NANOSTRUCTURED CUO; SOLUTION ROUTE; CU(OH)(2); FILM; STORAGE; CELLS; OXIDE;
D O I
10.1016/j.jallcom.2011.07.109
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A simple solution route is used to synthesize ultrafine Cu(OH)(2) nanowires by restraining the morphology transformation of early formed 1D nanostructure. The obtained ultrafine nanowires can be well preserved at a low temperature structure transformation in solid state. As anode material for lithium-ion batteries, the ultrafine CuO nanowires exhibit high reversible capacity, superior cycling performance and improved rate capability. The improved electrochemical properties of CuO nanowires are ascribed to their ultrafine size which lead to the reduced over-potential, extra reversible reactions at low potentials and improved interface performance between the electrode and electrolyte. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:9798 / 9803
页数:6
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