Nanostructures Generated from Photopolymerization of Poly(ethylene glycol) Diacrylate Templated from Hexagonal Lyotropic Liquid Crystals

被引：4

作者：

Zhang, Juan ^{[1
,2
]}

Xie, Zongli ^{[2
]}

She, Feng Hua ^{[1
]}

Hoang, Manh ^{[2
]}

Hill, Anita J. ^{[2
]}

Gao, Wei Min ^{[1
]}

Kong, Ling Xue ^{[1
]}

机构：

[1] Deakin Univ, Ctr Mat & Fibre Innovat, Geelong, Vic 3217, Australia

[2] CSIRO Mat Sci & Engn, Clayton, Vic, Australia

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2011年 / 120卷 / 03期

关键词：

nanotechnology; lyotropic liquid crystals; phase behavior; photopolymerization; POLYMER MEMBRANES; CARBON NANOTUBES; MICROEMULSIONS; FLOW;

D O I：

10.1002/app.33397

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The use of lyotropic liquid crystals (LLC) as a template to form periodic nanostructu.res in polymer materials is a promising technology. In this study, crosslinked poly(ethylene glycol) diacrylate nanostructured materials were prepared by photopolymerization in LLC hexagonal phases. Polarized light microscopy and small-angle powder X-ray diffraction were used to understand the original LLC order retention on photopolymerization, and scanning electron microscope was used to investigate the morphology under different purifying solvents and drying conditions. A Quantachrome Autosorb 1 system was used to study the pore size distribution of samples. It was found that the LLC hexagonal structure was retained to a great extent after photopolymerization. The formation of nanostructures was affected by purifying solvent and drying condition. The nanostructure synthesized from LLC with favorably aligned nanopores will find increasing applications in gas and water filtration, biology, and health science. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 120: 1817-1821, 2011

引用

页码：1817 / 1821

页数：5

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