The effects of thionyl chloride on the properties of graphene and graphene-carbon nanotube composites

被引：66

作者：

Wassei, Jonathan K. ^{[2
,3
]}

Cha, Kitty C. ^{[1
,2
]}

Tung, Vincent C. ^{[1
,2
]}

Yang, Yang ^{[1
,2
]}

Kaner, Richard B. ^{[1
,2
,3
]}

机构：

[1] Univ Calif Los Angeles, Dept Mat Sci & Engn, Los Angeles, CA 90024 USA

[2] Univ Calif Los Angeles, Calif NanoSyst Inst, Los Angeles, CA USA

[3] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90024 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2011年 / 21卷 / 10期

关键词：

TRANSPARENT;

D O I：

10.1039/c0jm02910f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Anionic dopants have been used to reduce the overall sheet resistance of carbon nanotube and graphene films for transparent conductor applications. These enhanced electronic properties are attributed to an increased number of p-type charge carriers. While there have been many reports of its use, there is little reported insight into the chemical interactions of a commonly used dopant, thionyl chloride (SOCl2), with pristine graphene and its chemically converted derivatives. Here, we explore the effects of thionyl chloride on the physical and chemical properties of graphene and hybrid graphene-carbon nanotube films, focusing on how the changes in conductivity correlate to the morphology of chemically converted graphene and carbon nanotube composites.

引用

页码：3391 / 3396

页数：6

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