{μ-6,6′-Dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}methanol-μ-nitrato-dinitratocopper(II)europium(III)

被引：4
|
作者：
Bao, Yan [1 ]
Li, Guang-Ming [1 ]
Yang, Fan [1 ]
Yan, Peng-Fei [1 ]
Chen, Peng [1 ]
机构：
[1] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
基金：
中国国家自然科学基金;
关键词：
MAGNETIC-PROPERTIES; COMPLEXES;
D O I：
10.1107/S1600536810039103
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title dinuclear salen- type complex, [CuEu(C22H24N2O4)(NO3)(3)(CH3OH)], the Cu-II ion is five-coordinated to two imine N atoms and two phenolate O atoms and one O from the bridging nitrate group. The Eu-III ion is ligated to three nitrate groups, four O atoms from the salen-type ligand and one methanol molecule, leading to a distorted tenfold coordination for the rare earth cation. One of the three nitrate anions is disordered over two positions in a 0.66 (5):0.34 (5) ratio.
引用
收藏
页码：M1379 / U410
页数：12
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