Hydrothermal synthesis, crystal structure and properties of Ag(I)-4f compounds based on 1H-benzimidazole-5,6-dicarboxylic acid

被引：42

作者：

Sun, Ya-guang ^{[1
]}

Wu, Yong-li ^{[1
]}

Xiong, Gang ^{[1
]}

Smet, Philippe F. ^{[2
]}

Ding, Fu ^{[1
]}

Guo, Mei-yan ^{[1
]}

Zhu, Ming-chang ^{[1
]}

Gao, En-jun ^{[1
]}

Poelman, Dirk ^{[2
]}

Verpoort, Francis ^{[3
]}

机构：

[1] Shenyang Inst Chem Technol, Lab Coordinat Chem, Shenyang 100142, Peoples R China

[2] Univ Ghent, Dept Solid State Sci, LumiLab, B-9000 Ghent, Belgium

[3] Univ Ghent, Dept Inorgan & Phys Chem, B-9000 Ghent, Belgium

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 47期

关键词：

HETEROMETALLIC COORDINATION POLYMERS; METAL-ORGANIC FRAMEWORKS; O-DONOR LIGANDS; MAGNETIC-PROPERTIES; HYDROGEN STORAGE; IMIDAZOLATE FRAMEWORKS; BUILDING-BLOCKS; N-DONOR; LANTHANIDE; LN;

D O I：

10.1039/c0dt00579g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Seven novel heterometallic coordination polymers [CeAg(Hbidc)(2)(H2O)(2)](1) and [LnAg(Hbidc)(2)]center dot 3(H2O)[Ln = Sm (2), Gd (3), Tb (4), Dy (5), Ho (6), Er (7), H(3)bidc = 1H-benzimidazole-5,6-dicarboxylic acid] have been synthesized under hydrothermal conditions and characterized by elemental analysis, FT-IR, TG analysis, and single crystal X-ray diffraction. X-Ray analysis revealed that the seven complexes present two different types of three-dimensional (3D) structures. Complex 1 crystallized in an orthorhombic manner having a Pna2(1) space group, consisting of a 3D framework with a 1D heterometallic chain. Polymers 2-7 are isostructural and crystallized in an orthorhombic fashion having a Pccn space group existing of a two-fold interpenetrating 3D framework. The luminescence properties and the magnetic properties of all polymers were investigated.

引用

页码：11383 / 11395

页数：13

共 104 条

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