SnS 3D Flowers with Superb Kinetic Properties for Anodic Use in Next-Generation Sodium Rechargeable Batteries

被引:96
作者
Cho, Eunbi [1 ]
Song, Kyeongse [1 ]
Park, Mi Hui [1 ]
Nam, Kyung-Wan [1 ]
Kang, Yong-Mook [1 ]
机构
[1] Univ Dongguk, Dept Energy & Mat Engn, Seoul 100715, South Korea
基金
新加坡国家研究基金会;
关键词
NA-ION BATTERIES; HIGH-CAPACITY; ENERGY-STORAGE; ELECTROCHEMICAL PERFORMANCE; RATE CAPABILITY; LOW-COST; CATHODE; CHALLENGES; NA0.44MNO2; NANOSHEETS;
D O I
10.1002/smll.201503168
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tin sulfide (SnS) 3D flowers containing hierarchical nanosheet subunits are synthesized using a simple polyol process. The Li ion cells incorporating SnS 3D flowers exhibit an excellent rate capability, as well as good cycling stability, compared to SnS bulks and Sn nanoparticles. These desirable properties can be attributed to their unique morphology having not only large surface reaction area but also enough space between individual 2D nanosheets, which alleviates the pulverization of SnS.
引用
收藏
页码:2510 / 2517
页数:8
相关论文
共 41 条
  • [1] A short review on the comparison between Li battery systems and rechargeable magnesium battery technology
    Aurbach, D
    Gofer, Y
    Lu, Z
    Schechter, A
    Chusid, O
    Gizbar, H
    Cohen, Y
    Ashkenazi, V
    Moshkovich, M
    Turgeman, R
    Levi, E
    [J]. JOURNAL OF POWER SOURCES, 2001, 97-8 : 28 - 32
  • [2] Berthelot R, 2011, NAT MATER, V10, P74, DOI [10.1038/nmat2920, 10.1038/NMAT2920]
  • [3] Metal-air batteries: from oxygen reduction electrochemistry to cathode catalysts
    Cheng, Fangyi
    Chen, Jun
    [J]. CHEMICAL SOCIETY REVIEWS, 2012, 41 (06) : 2172 - 2192
  • [4] A Critical Review of Li/Air Batteries
    Christensen, Jake
    Albertus, Paul
    Sanchez-Carrera, Roel S.
    Lohmann, Timm
    Kozinsky, Boris
    Liedtke, Ralf
    Ahmed, Jasim
    Kojic, Aleksandar
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (02) : R1 - R30
  • [5] Excellent electrochemical performance of tin monosulphide (SnS) as a sodium-ion battery anode
    Dutta, Prasit Kumar
    Sen, Uttam Kumar
    Mitra, Sagar
    [J]. RSC ADVANCES, 2014, 4 (81): : 43155 - 43159
  • [6] Sodium and sodium-ion energy storage batteries
    Ellis, Brian L.
    Nazar, Linda F.
    [J]. CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2012, 16 (04) : 168 - 177
  • [7] Challenges in the development of advanced Li-ion batteries: a review
    Etacheri, Vinodkumar
    Marom, Rotem
    Elazari, Ran
    Salitra, Gregory
    Aurbach, Doron
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) : 3243 - 3262
  • [8] Charge carriers in rechargeable batteries: Na ions vs. Li ions
    Hong, Sung You
    Kim, Youngjin
    Park, Yuwon
    Choi, Aram
    Choi, Nam-Soon
    Lee, Kyu Tae
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (07) : 2067 - 2081
  • [9] Ab Initio Study of the Sodium Intercalation and Intermediate Phases in Na0.44MnO2 for Sodium-Ion Battery
    Kim, Heejin
    Kim, Dong Jun
    Seo, Dong-Hwa
    Yeom, Min Sun
    Kang, Kisuk
    Kim, Do Kyung
    Jung, Yousung
    [J]. CHEMISTRY OF MATERIALS, 2012, 24 (06) : 1205 - 1211
  • [10] Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
    Kim, Sung-Wook
    Seo, Dong-Hwa
    Ma, Xiaohua
    Ceder, Gerbrand
    Kang, Kisuk
    [J]. ADVANCED ENERGY MATERIALS, 2012, 2 (07) : 710 - 721