Uniform wrapping of copper(i) oxide nanocubes by self-controlled copper-catalyzed azide-alkyne cycloaddition toward selective carbon dioxide electrocatalysis

被引：2

作者：

Umeda, Takuma ^{[1
]}

Kurome, Takeshi ^{[1
]}

Sakatmoto, Ayumu ^{[1
]}

Kubo, Kazuyuki ^{[1
]}

Mizuta, Tsutomu ^{[1
]}

Son, Seung Uk ^{[2
]}

Kume, Shoko ^{[1
]}

机构：

[1] Hiroshima Univ, Grad Sch Adv Sci & Engn, Dept Chem, 1-3-1 Kagamiyama, Higashihiroshima 7398526, Japan

[2] Sungkyunkwan Univ, Dept Chem, Suwon 16419, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 58期

关键词：

ELECTROCHEMICAL REDUCTION; CLICK CHEMISTRY; CO2; REDUCTION; ELECTROREDUCTION; NANOCRYSTALS; ELECTRODES; AZOLES; DFT;

D O I：

10.1039/d2cc02017c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper(i) oxide nanocubes were wrapped with an extremely uniform organic layer grown by self-controlled, Cu-mediated catalysis. This layer aided in retaining the initial cubic structure of the copper nanocubes during their use as a CO2 reduction electrocatalyst, resulting in high CO2 reduction selectivity by strong suppression of hydrogen evolution because of exclusion of water from the surface.

引用

页码：8053 / 8056

页数：5

共 54 条

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