Effect of various structure directing agents on the properties of nanostructured conducting polyaniline

被引:1
作者
Saini, Deepshikha [2 ]
Priydarshi, Manish. Kr. [1 ]
Basu, Tinku [1 ]
机构
[1] Amity Univ, Amity Inst Nanotechnol, Noida, Uttar Pradesh, India
[2] Amity Univ, Amity Inst Biotechnol, Noida, Uttar Pradesh, India
关键词
nanoparticles; polyaniline; SDA; structure directing agents; morphology; polydispersity; NANOPARTICLES; COMPOSITES;
D O I
10.1504/IJNT.2012.049461
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this study the effects of various structure directing agents on the size, morphology, chemical structure and electronic properties of various (Nano Structured Polyaniline) NSPANI were investigated. A number of chemical synthesis of NSPANI were carried out using various Structure Directing Agents (SDA) like Sodium Dodecyl Sulphate (SDS), Sodium Dodecyl Benzene Sulphonate (SDBS) and Camphor Sulphonic Acid (CSA). The resulting NSPANI were characterised by UV-Visible spectroscopy, Fourier Transform Infrared Spectroscopy (FTIR), Transmission Electron Microscopy (TEM), Dynamic Light Scattering (DLS), Atomic Force Microscopy (AFM), X-Ray Diffraction (XRD) and I-V characteristics. Smallest spherical poly aniline nano particles are formed when SDBS is used as SDA as well as dopant. When CSA is used as a dopant, the particle size increases but the morphology of the NSPANI changes from fibrous to spherical.
引用
收藏
页码:995 / 1006
页数:12
相关论文
共 30 条
[1]   Doping of polyaniline films with organic sulfonic acids in aqueous media and the effect of water on these doped films [J].
Ayad, Mohamad M. ;
Zaki, Eman A. .
EUROPEAN POLYMER JOURNAL, 2008, 44 (11) :3741-3747
[2]   Blends of HCl-doped polyaniline nanoparticles and poly(vinyl chloride) with extremely low percolation threshold - A morphology study [J].
Banerjee, P ;
Mandal, BM .
SYNTHETIC METALS, 1995, 74 (03) :257-261
[3]   Alternating electrical conductivity of polyaniline [J].
Bianchi, RF ;
Ferreira, GFL ;
Lepienski, CM ;
Faria, RM .
JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (09) :4602-4607
[4]   LIQUID-CRYSTALLINE SOLUTIONS OF ELECTRICALLY CONDUCTING POLYANILINE [J].
CAO, Y ;
SMITH, P .
POLYMER, 1993, 34 (15) :3139-3143
[5]   Biocatalytic approaches for synthesis of conducting polyaniline nanoparticles [J].
Cholli, AL ;
Thiyagarajan, M ;
Kumar, J ;
Parmar, VS .
PURE AND APPLIED CHEMISTRY, 2005, 77 (01) :339-344
[6]   Electrosynthesis and characterisation of nanostructured palladium-polypyrrole composites [J].
Cioffi, N ;
Torsi, L ;
Sabbatini, L ;
Zambonin, PG ;
Bleve-Zacheo, T .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2000, 488 (01) :42-47
[7]   Nanostructured palladium-polypyrrole composites electrosynthesised from organic solvents [J].
Cioffi, N ;
Torsi, L ;
Losito, I ;
Sabbatini, L ;
Zambonin, PG ;
Bleve-Zacheo, T .
ELECTROCHIMICA ACTA, 2001, 46 (26-27) :4205-4211
[8]   Vibrational spectroscopic characterisation of protonic conducting polyethyleneimine-alpha- and gamma-zirconium phosphate nanocomposites [J].
Costantino, U ;
Casciola, M ;
Pani, G ;
Jones, DJ ;
Roziere, J .
SOLID STATE IONICS, 1997, 97 (1-4) :261-267
[9]   Physical and electrochemical characterization of nanostructured composites formed by TiO2 templates and PEDOT-PPS films [J].
Cuentas-Gallegos, A. K. ;
Rincon, M. E. ;
Orozco-Gamboa, G. .
ELECTROCHIMICA ACTA, 2006, 51 (18) :3794-3801
[10]   Electronic and mass transport in ion beam nanostructured polymers: Role of the irradiation energy [J].
Davenas, J ;
Boiteux, G ;
Jardin, C .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1997, 131 (1-4) :91-96