Recent advances with π-conjugated salen systems

被引：226

作者：

Whiteoak, Christopher J. ^{[1
]}

Salassa, Giovanni ^{[1
]}

Kleij, Arjan W. ^{[1
,2
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] Catalan Inst Res & Adv Studies ICREA, Barcelona 08010, Spain

来源：

CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 02期

关键词：

SCHIFF-BASE MACROCYCLES; RING-OPENING REACTIONS; SALPHEN COMPLEXES; CARBON-DIOXIDE; EFFICIENT OXIDATION; CATION FORMATION; BUILDING-BLOCKS; CATALYSTS; EPOXIDATION; COPOLYMERIZATION;

D O I：

10.1039/c1cs15170c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Schiff base ligands have long been successfully employed as ligands in combination with various metals to give catalysts capable of realizing a variety of synthetic transformations. One of the most widely used Schiff base ligands, the "salen'' ligand, has been extensively researched. Recently, there has been increased interest in pi-conjugated salen systems, known as "salphen'' ligands, as a result of the differences in reactivity of the complexes in catalytic applications compared with the salen analogues. Complexes of salphen ligands display interesting photophysical and supramolecular properties which are not always observed with salen systems as a result of their pi-conjugation. This tutorial review therefore describes the most significant advances recently made with salphen and related pi-conjugated ligand systems.

引用

页码：622 / 631

页数：10

共 65 条

[11] Efficient carbonate synthesis under mild conditions through cycloaddition of carbon dioxide to oxiranes using a Zn(salphen) catalyst [J].

Decortes, Antonello ;

Martinez Belmonte, Marta ;

Benet-Buchholz, Jordi ;

Kleij, Arjan W. .

CHEMICAL COMMUNICATIONS, 2010, 46 (25) :4580-4582

[12] DMAP/Cr(III) catalyst ratio:: The decisive factor for poly(propylene carbonate) formation in the coupling of CO2 and propylene oxide [J].

Eberhardt, R ;

Allmendinger, M ;

Rieger, B .

MACROMOLECULAR RAPID COMMUNICATIONS, 2003, 24 (02) :194-196

[13] Axial ligand control over monolayer and bilayer formation of metal-salophens at the liquid-solid interface [J].

Elemans, Johannes A. A. W. ;

Wezenberg, Sander J. ;

Coenen, Michiel J. J. ;

Escudero-Adan, Eduardo C. ;

Benet-Buchholz, Jordi ;

den Boer, Duncan ;

Speller, Sylvia ;

Kleij, Arjan W. ;

De Feyter, Steven .

CHEMICAL COMMUNICATIONS, 2010, 46 (15) :2548-2550

[14] A Short Desymmetrization Protocol for the Coordination Environment in Bis-salphen Scaffolds [J].

Escudero-Adan, Eduardo C. ;

Martinez Belmonte, Marta ;

Martin, Eddy ;

Salassa, Giovanni ;

Benet-Buchholz, Jordi ;

Kleij, Arjan W. .

JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (13) :5404-5412

[15] Practical Approach to Structurally Diverse Monoimine Salts and Nonsymmetrical Metallosalphen Complexes [J].

Escudero-Adan, Eduardo C. ;

Martinez Belmonte, Marta ;

Benet-Buchholz, Jordi ;

Kleij, Arjan W. .

ORGANIC LETTERS, 2010, 12 (20) :4592-4595

[16] Trapping of a Four-Coordinate Zinc Salphen Complex Inside a Crystal Matrix [J].

Escudero-Adan, Eduardo C. ;

Benet-Buchholz, Jordi ;

Kleij, Arjan W. .

CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (17) :4233-4237

[17] Templated encapsulation of pyridyl-bian palladium complexes:: Tunable catalysts for CO/4-tert-butylstyrene copolymerization [J].

Flapper, Jitte ;

Reek, Joost N. H. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (45) :8590-8592

[18] Reversible-irreversible approach to Schiff base macrocycles: Access to isomeric macrocycles with multiple salphen pockets [J].

Frischmann, Peter D. ;

Jiang, Jian ;

Hui, Joseph K. -H. ;

Grzybowski, Joseph J. ;

MacLachlan, Mark J. .

ORGANIC LETTERS, 2008, 10 (06) :1255-1258

[19] Capsule Formation, Carboxylate Exchange, and DFT Exploration of Cadmium Cluster Metallocavitands: Highly Dynamic Supramolecules [J].

Frischmann, Peter D. ;

Facey, Glenn A. ;

Ghi, Phuong Y. ;

Gallant, Amanda J. ;

Bryce, David L. ;

Lelj, Francesco ;

MacLachlan, Mark J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (11) :3893-3908

[20] Axially rotating (Pt-salphen)2 phosphorescent coordination frameworks [J].

Guo, Zhengqing ;

Tong, Wah-Leung ;

Chan, Michael C. W. .

CHEMICAL COMMUNICATIONS, 2009, (41) :6189-6191

← 1 2 3 4 5 6 7 →