Experimental determination of the full Landau potential of bent-core doped ferroelectric liquid crystals

被引:23
作者
Archer, P [1 ]
Dierking, I [1 ]
机构
[1] Univ Manchester, Sch Phys & Astron, Manchester M13 9PL, Lancs, England
来源
PHYSICAL REVIEW E | 2005年 / 72卷 / 04期
关键词
D O I
10.1103/PhysRevE.72.041713
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
The full Landau potential of a ferroelectric liquid crystal, doped with two different bent-core molecules at varying concentration, was determined experimentally. Using a multicurve fitting procedure, temperature and electric field dependent tilt angle and polarization measurements were analyzed according to the generalized Landau model of ferroelectric liquid crystals. From this analysis the three Landau coefficients as well as the polarization-tilt coupling parameters were obtained as a function of dopant concentration. It is shown that the two most varied parameters are those of the first Landau coefficient and the (chiral) linear polarization-tilt coupling constant. The results quantitatively verify the chiral induction capability of nonchiral bent-core shaped dopants and an observed increase in the electroclinic effect with increasing dopant concentration.
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页数:10
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共 32 条
[1]   OPTICAL AND DIELECTRIC INVESTIGATIONS ON THE ELECTROCLINIC EFFECT EXHIBITED BY A FERROELECTRIC LIQUID-CRYSTAL WITH HIGH SPONTANEOUS POLARIZATION [J].
BAHR, C ;
HEPPKE, G .
LIQUID CRYSTALS, 1987, 2 (06) :825-831
[2]   CHIRAL-RACEMIC PHASE-DIAGRAM OF A FERROELECTRIC LIQUID-CRYSTAL WITH HIGH SPONTANEOUS POLARIZATION [J].
BAHR, C ;
HEPPKE, G ;
SABASCHUS, B .
FERROELECTRICS, 1988, 84 :103-118
[3]   SMECTIC-A SMECTIC-C TRANSITION - MEAN FIELD OR CRITICAL [J].
BIRGENEAU, RJ ;
GARLAND, CW ;
KORTAN, AR ;
LITSTER, JD ;
MEICHLE, M ;
OCKO, BM ;
ROSENBLATT, C ;
YU, LJ ;
GOODBY, J .
PHYSICAL REVIEW A, 1983, 27 (02) :1251-1254
[4]   DEPENDENCE OF THE TILT ANGLE ON EXTERNAL FORCES FOR SMECTIC-C AND CHIRAL SMECTIC-C LIQUID-CRYSTALS - MEASUREMENT OF THE HEAT-CAPACITY OF DOBAMBC [J].
CARLSSON, T ;
DAHL, I .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1983, 95 (3-4) :373-400
[5]   GENERALIZED LANDAU MODEL OF FERROELECTRIC LIQUID-CRYSTALS [J].
CARLSSON, T ;
ZEKS, B ;
LEVSTIK, A ;
FILIPIC, C ;
LEVSTIK, I ;
BLINC, R .
PHYSICAL REVIEW A, 1987, 36 (03) :1484-1487
[6]   SUBMICROSECOND BISTABLE ELECTRO-OPTIC SWITCHING IN LIQUID-CRYSTALS [J].
CLARK, NA ;
LAGERWALL, ST .
APPLIED PHYSICS LETTERS, 1980, 36 (11) :899-901
[7]   TILT-ANGLE, POLARIZATION, AND HEAT-CAPACITY MEASUREMENTS NEAR THE SMECTIC-A CHIRAL-SMECTIC-C PHASE-TRANSITION OF PARA-(NORMAL-DECYLOXYBENZYLIDENE)-PARA-AMINO-(2-METHYLBUTYL)CINNAMATE (DOBAMBC) [J].
DUMRONGRATTANA, S ;
HUANG, CC ;
NOUNESIS, G ;
LIEN, SC ;
VINER, JM .
PHYSICAL REVIEW A, 1986, 34 (06) :5010-5019
[8]   Induced and spontaneous deracemization in bent-core liquid crystal phases and in other phases doped with bent-core molecules [J].
Earl, DJ ;
Osipov, MA ;
Takezoe, H ;
Takanishi, Y ;
Wilson, MR .
PHYSICAL REVIEW E, 2005, 71 (02)
[9]   Predictions of molecular chirality and helical twisting powers: A theoretical study [J].
Earl, DJ ;
Wilson, MR .
JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (19) :10280-10288
[10]   ELECTRO-CLINIC EFFECT AT AC PHASE-CHANGE IN A CHIRAL SMECTIC LIQUID-CRYSTAL [J].
GAROFF, S ;
MEYER, RB .
PHYSICAL REVIEW LETTERS, 1977, 38 (15) :848-851