Conjugate addition of arylboronic acids to α,β-unsaturated carbonyl compounds in aqueous medium using Pd(II) complexes with dihydroxy-2,2′-bipyridine ligands: homogeneous or heterogeneous nano-catalysis?

被引：18

作者：

Tomas-Mendivil, Eder ^{[1
]}

Diez, Josefina ^{[1
]}

Cadierno, Victorio ^{[1
]}

机构：

[1] Univ Oviedo, IUQOEM, Dept Quim Organ & Inorgan, E-33006 Oviedo, Spain

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2011年 / 1卷 / 09期

关键词：

ASYMMETRIC 1,4-ADDITION; ORGANOBORONIC ACIDS; COUPLING REACTIONS; NANOPARTICLES; SURFACTANT; ALDEHYDES; ENONES; WATER; ARYLSILOXANES; CHEMISTRY;

D O I：

10.1039/c1cy00214g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The conjugate addition of arylboronic acids to alpha,beta-unsaturated carbonyl compounds in water under air has been studied using a series of palladium(II) derivatives containing symmetrically disubstituted-2,20-bipyridine ligands. Among them, best results were obtained with complex [PdCl2{3,30-(OH)(2)-2,20-bipy}] (2a), which selectively provides the desired addition products in good to high yields under mild conditions. Catalytically active palladium nanoparticles are formed in the course of the reactions. In the presence of sodium dodecyl sulfate (SDS) these nanoparticles can be stabilized and recycled.

引用

页码：1605 / 1615

页数：11