Adsorption of Cr(VI) and Speciation of Cr(VI) and Cr(III) in Aqueous Solutions Using Chemically Modified Chitosan

被引：70

作者：

Dai, Jun ^{[1
,2
]}

Ren, FengLian ^{[1
]}

Tao, ChunYuan ^{[2
]}

机构：

[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China

[2] JiuJiang Univ, Coll Chem & Chem Engn, Jiujiang 332005, Jiangxi, Peoples R China

来源：

INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH | 2012年 / 9卷 / 05期

关键词：

grafting chitosan; speciation; flame atomic absorption spectrometry; chromium; LIQUID-LIQUID-EXTRACTION; SOLID-PHASE EXTRACTION; METAL-IONS; CHROMIUM; SAMPLES; PRECONCENTRATION; TOXICITY; BEHAVIOR; COLUMN; WATER;

D O I：

10.3390/ijerph9051757

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

A new type of grafting chitosan (CTS) was synthesized using 2-hydroxyethyltrimethyl ammonium chloride (HGCTS). The adsorption of Cr(VI) on HGCTS was studied. The effect factors on adsorption and the adsorption mechanism were considered. The results indicated that the HGCTS could concentrate and separate Cr(VI) at pH 4.0; the adsorption equilibrium time was 80 min; the maximum adsorption capacity was 205 mg/g. The adsorption isotherm and kinetics were investigated, equilibrium data agreed very well with the Langmuir model and the pseudo second-order model could describe the adsorption process better than the pseudo first-order model. A novel method for speciation of Cr(VI) and Cr(III) in environmental water samples has been developed using HGCTS as adsorbent and FAAS as determination means. The detection limit of this method was 20 ng/L, the relatively standard deviation was 1.2% and the recovery was 99%similar to 105%.

引用

页码：1757 / 1770

页数：14

共 30 条

[1] Ana C.Z., 2010, J HAZARD MATER, V2, P1
[2] A novel multi-element coprecipitation technique for separation and enrichment of metal ions in environmental samples
Aydin, Funda Armagan
Soylak, Mustafa
[J]. TALANTA, 2007, 73 (01) : 134 - 141
[3] Speciation of hexavalent chromium in waters by liquid-liquid extraction and GFAAS determination
Beni, Aron
Karosi, Roland
Posta, Jozsef
[J]. MICROCHEMICAL JOURNAL, 2007, 85 (01) : 103 - 108
[4] Speciation of Cr(III) and Cr(VI) after column solid phase extraction on Amberlite XAD-2010
Bulut, V. N.
Duran, C.
Tufekci, M.
Elci, L.
Soylak, M.
[J]. JOURNAL OF HAZARDOUS MATERIALS, 2007, 143 (1-2) : 112 - 117
[5] A new approach for the flocculation mechanism of chitosan
Chen, L
Chen, DH
Wu, CL
[J]. JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2003, 11 (03) : 87 - 92
[6] Adsorption behavior of reactive dye in aqueous solution on chemical cross-linked chitosan beads
Chiou, MS
Li, HY
[J]. CHEMOSPHERE, 2003, 50 (08) : 1095 - 1105
[7] Speciation of Mn(II), Mn(VII) and total manganese in water and food samples by coprecipitation-atomic absorption spectrometry combination
Citak, Demirhan
Tuzen, Mustafa
Soylak, Mustafa
[J]. JOURNAL OF HAZARDOUS MATERIALS, 2010, 173 (1-3) : 773 - 777
[8] Application of a carbon sorbent for the removal of cadmium and other heavy metal ions from aqueous solution
El-Shafey, E
Cox, M
Pichugin, AA
Appleton, Q
[J]. JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2002, 77 (04) : 429 - 436
[9] Removal of Cr(VI) from alkaline aqueous solutions using chemically modified magnetic chitosan resins
Elwakeel, Khalid Z.
[J]. DESALINATION, 2010, 250 (01) : 105 - 112
[10] Guibal E, 2000, J APPL POLYM SCI, V75, P119, DOI 10.1002/(SICI)1097-4628(20000103)75:1<119::AID-APP14>3.3.CO

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