Boron adsorption by clinoptilolite using factorial design

被引:10
作者
Kavak, Duygu [1 ]
机构
[1] Eskisehir Osmangazi Univ, Dept Chem Engn, TR-26480 Meselik, Eskisehir, Turkey
关键词
boron removal; adsorption; clinoptilolite; experimental design; AQUEOUS-SOLUTIONS; BATCH ADSORPTION; REMOVAL; FULL; EXCHANGE; WATER; ELECTROCOAGULATION; ELECTRODIALYSIS; SORPTION;
D O I
10.1002/ep.10500
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this article, boron removal from aqueous solutions by batch adsorption was investigated and 23 full factorial design was applied. Three parameters affected the performance and two levels of these parameters were investigated. The chosen parameters were temperature (25 degrees C and 45 degrees C), pH (3 and 7), and mass of adsorbent (0.1 g and 1 g). The significance of the effects was checked by analysis of variance (MINITAB-Version 15). The model-function equation for boron adsorption on clinoptilolite was obtained. The results showed that temperature, pH, and mass of adsorbent affected boron removal by adsorption. Boron removal increased with increasing pH and adsorbent dosage, but decreased with increasing temperature. The optimum conditions were found as pH = 7, adsorbent dosage = 1 g/25 mL solution, and temperature = 25 degrees C by using factorial design. In addition, the effects of pH, temperature, adsorbent dosage, and initial boron concentration on boron removal were investigated. The adsorption isotherm studies were also performed. Maximum adsorbent capacity (qo) was calculated as 3.64 mg/g. (C) 2010 American Institute of Chemical Engineers Environ Prog, 2010
引用
收藏
页码:527 / 532
页数:6
相关论文
共 25 条
[1]   Packed-bed sorption of copper using spent animal bones: factorial experimental design, desorption and column regeneration [J].
Al-Asheh, S ;
Abdel-Jabar, N ;
Banat, F .
ADVANCES IN ENVIRONMENTAL RESEARCH, 2002, 6 (03) :221-227
[2]   Donnan dialysis of borate anions through anion exchange membranes: A new method for regeneration of boron selective resins [J].
Bryjak, Marek ;
Pozniak, Gryzelda ;
Kabay, Nalan .
REACTIVE & FUNCTIONAL POLYMERS, 2007, 67 (12) :1635-1642
[3]   Boron removal from aqueous solutions by activated carbon impregnated with salicylic acid [J].
Celik, Z. Ceylan ;
Can, B. Z. ;
Kocakerim, M. Muhtar .
JOURNAL OF HAZARDOUS MATERIALS, 2008, 152 (01) :415-422
[4]   Removal of boron from aqueous solution by using neutralized red mud [J].
Cengeloglu, Yunus ;
Tor, Ali ;
Arslan, Gulsin ;
Ersoz, Mustafa ;
Gezgin, Sait .
JOURNAL OF HAZARDOUS MATERIALS, 2007, 142 (1-2) :412-417
[5]   Removal of Ga(III) from aqueous solution by adsorption on activated bentonite using a factorial design [J].
Chegrouche, S ;
Bensmaili, A .
WATER RESEARCH, 2002, 36 (11) :2898-2904
[6]   Characterization and ethylene adsorption of natural and modified clinoptilolites [J].
Erdogan, Burcu ;
Sakizci, Meryem ;
Yoeruekogullari, Ertugrul .
APPLIED SURFACE SCIENCE, 2008, 254 (08) :2450-2457
[7]  
Ferreira OP, 2006, CHEMOSPHERE, V62, P80, DOI 10.1016/j.chemosphere.2005.04.009
[8]   Electrocoagulation of some reactive dyes:: a statistical investigation of some electrochemical variables [J].
Gürses, A ;
Yalçin, M ;
Dogar, C .
WASTE MANAGEMENT, 2002, 22 (05) :491-499
[9]   Removal of boron from water by electrodialysis: effect of feed characteristics and interfering ions [J].
Kabay, N. ;
Arar, O. ;
Acar, F. ;
Ghazal, A. ;
Yuksel, U. ;
Yuksel, M. .
DESALINATION, 2008, 223 (1-3) :63-72
[10]   Removal of boron from aqueous solutions by batch adsorption on calcined alunite using experimental design [J].
Kavak, Duygu .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 163 (01) :308-314