Microwave-assisted Claisen and aza-Claisen rearrangements

被引：19
作者：
Tymoshenko, Dmytro O. [1 ]
机构：
[1] AMRI, Dept Med Chem, Albany, NY 12203 USA
来源：
MINI-REVIEWS IN ORGANIC CHEMISTRY | 2008年 / 5卷 / 02期
关键词：
Claisen rearrangement; microwave; irradiation; natural compounds;
D O I：
10.2174/157019308784223587
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review covers the key advances in the study of Claisen rearrangement under microwave irradiation conditions. It surveys [3,3] sigmatropic rearrangements of vinyl allyl ethers, aryl allyl ethers, ortho-ester and aza Claisen rearrangements. Applications of the method for the synthesis of heterocyclic and natural compounds are surveyed.
引用
收藏
页码：85 / 95
页数：11
相关论文
共 98 条
  • [1] Microwave assisted medicinal chemistry
    Alcazar, Jesus
    Diels, Gaston
    Schoentjes, Bruno
    [J]. MINI-REVIEWS IN MEDICINAL CHEMISTRY, 2007, 7 (04) : 345 - 369
  • [2] Development and synthetic applications of asymmetric [3,3]-sigmatropic rearrangments
    Allin, SM
    Baird, RD
    [J]. CURRENT ORGANIC CHEMISTRY, 2001, 5 (04) : 395 - 415
  • [3] Applications of high-temperature aqueous media for synthetic organic reactions
    An, JY
    Bagnell, L
    Cablewski, T
    Strauss, CR
    Trainor, RW
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (08) : 2505 - 2511
  • [4] The combinatorial synthesis of purine, pyrimidine and triazinebased libraries
    Bork, JT
    Lee, JW
    Chang, YT
    [J]. QSAR & COMBINATORIAL SCIENCE, 2004, 23 (04): : 245 - 260
  • [5] A [3,3]-sigmatropic process catalysed by acetate. The decarboxylative Claisen rearrangement
    Bourgeois, D
    Craig, D
    Grellepois, F
    Mountford, DM
    Stewart, AJW
    [J]. TETRAHEDRON, 2006, 62 (2-3) : 483 - 495
  • [6] Synthesis of homoallylic sulfones through a decarboxylative Claisen rearrangement reaction
    Bourgeois, D
    Craig, D
    King, NP
    Mountford, DM
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (04) : 618 - 621
  • [7] Environmentally benign solvent systems: Toward a greener [4+2] cycloaddition process
    Brummond, K. M.
    Wach, C. K.
    [J]. MINI-REVIEWS IN ORGANIC CHEMISTRY, 2007, 4 (01) : 89 - 103
  • [8] MICROWAVE-ASSISTED ORGANIC-REACTIONS
    CADDICK, S
    [J]. TETRAHEDRON, 1995, 51 (38) : 10403 - 10432
  • [9] Claisen rearrangement over the past nine decades
    Castro, AMM
    [J]. CHEMICAL REVIEWS, 2004, 104 (06) : 2939 - 3002
  • [10] Selective α-monoallylation of phenyl ketones and benzocycloalkanones under microwave irradiation
    Cid, JM
    Romera, JL
    Trabanco, AA
    [J]. TETRAHEDRON LETTERS, 2004, 45 (06) : 1133 - 1136
12345678910