Group 4 Transition Metal Complexes with Anionic N-Heterocyclic Olefin Ligands

被引：3
|
作者：
Watson, Ian C. [1 ]
Zhou, Yuqiao [1 ]
Ferguson, Michael J. [1 ]
Rivard, Eric [1 ]
机构：
[1] Univ Alberta, Dept Chem, 11227 Saskatchewan Dr, Edmonton, AB T6G 2G2, Canada
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2022年 / 648卷 / 19期
基金：
加拿大自然科学与工程研究理事会;
关键词：
Anionic N-Heterocyclic Olefins; Group; 4; Metals; Zirconium(II); Reduction; TD-DFT; ZETA VALENCE QUALITY; GAUSSIAN-BASIS SETS; ATOMS LI; ZIRCONIUM; DINITROGEN; PHOSPHINE; DEHYDROGENATION; CATALYSIS; COORDINATION; DERIVATIVES;
D O I：
10.1002/zaac.202200082
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of anionic N-heterocyclic olefin (aNHO)-supported Group 4 metal complexes was achieved by salt metathesis reactions between a lithiated aNHO and Group 4 metal tetrahalides. A ligand-activated bis-aNHO Zr(II) complex was also obtained and structurally characterized.
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页数：6
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