Group 4 Transition Metal Complexes with Anionic N-Heterocyclic Olefin Ligands

被引：3
|
作者：
Watson, Ian C. [1 ]
Zhou, Yuqiao [1 ]
Ferguson, Michael J. [1 ]
Rivard, Eric [1 ]
机构：
[1] Univ Alberta, Dept Chem, 11227 Saskatchewan Dr, Edmonton, AB T6G 2G2, Canada
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2022年 / 648卷 / 19期
基金：
加拿大自然科学与工程研究理事会;
关键词：
Anionic N-Heterocyclic Olefins; Group; 4; Metals; Zirconium(II); Reduction; TD-DFT; ZETA VALENCE QUALITY; GAUSSIAN-BASIS SETS; ATOMS LI; ZIRCONIUM; DINITROGEN; PHOSPHINE; DEHYDROGENATION; CATALYSIS; COORDINATION; DERIVATIVES;
D O I：
10.1002/zaac.202200082
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of anionic N-heterocyclic olefin (aNHO)-supported Group 4 metal complexes was achieved by salt metathesis reactions between a lithiated aNHO and Group 4 metal tetrahalides. A ligand-activated bis-aNHO Zr(II) complex was also obtained and structurally characterized.
引用
收藏
页数：6
相关论文
共 50 条
  • [1] Transition Metal Complexes of Anionic N-Heterocyclic Dicarbene Ligands
    Musgrave, Rebecca A.
    Turbervill, Robert S. P.
    Irwin, Mark
    Goicoechea, Jose M.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (43) : 10832 - 10835
  • [2] Transition metal complexes of multidentate N-heterocyclic carbene ligands and catalytic performance in olefin polymerization
    Lavoie, Gino G.
    Badaj, Anna C.
    Al Thagfi, Jameel
    Dastgir, Sarim
    Larocque, Timothy G.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [3] Group 7 transition metal complexes with N-heterocyclic carbenes
    Hock, Sebastian J.
    Schaper, Lars-Arne
    Herrmann, Wolfgang A.
    Kuehn, Fritz E.
    CHEMICAL SOCIETY REVIEWS, 2013, 42 (12) : 5073 - 5089
  • [4] N-Heterocyclic carbenes as supporting ligands in transition metal complexes of N2
    Ohki, Yasuhiro
    Seino, Hidetake
    DALTON TRANSACTIONS, 2016, 45 (03) : 874 - 880
  • [5] Early transition metal complexes featuring N-heterocyclic carbene ligands.
    Abernethy, CD
    Culver, JP
    Phillips, CR
    Thompson, KN
    Spicer, MD
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U1103 - U1104
  • [6] Transition Metal Complexes of N-Heterocyclic Germylenes
    Ullah, Farman
    Kuehl, Olaf
    Baior, Gabor
    Veszpremi, Tamas
    Jones, Peter G.
    Heinicke, Joachim
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (02) : 221 - 229
  • [7] Applications of metal N-heterocyclic carbene complexes in olefin polymerizations
    Feng, Ting
    Zhang, Le
    Wu, Shang-Xiao
    Shi, Xiaochao
    Han, Ying-Feng
    INORGANIC CHEMISTRY FRONTIERS, 2024, 11 (19): : 6246 - 6274
  • [8] N-heterocyclic carbene (NHC) complexes of group 4 transition metals
    Zhang, Dao
    Zi, Guofu
    CHEMICAL SOCIETY REVIEWS, 2015, 44 (07) : 1898 - 1921
  • [9] Bridged N-Heterocyclic/Mesoionic (NHC/MIC) Heterodicarbenes as Ligands for Transition Metal Complexes
    Mendoza-Espinosa, Daniel
    Alvarez-Hernandez, Alejandro
    Angeles-Beltran, Deyanira
    Negron-Silva, Guillermo E.
    Suarez-Castillo, Oscar R.
    Vasquez-Perez, Jose M.
    INORGANIC CHEMISTRY, 2017, 56 (04) : 2092 - 2099
  • [10] Group 6 metal alkylidene and alkylidyne N-heterocyclic carbene complexes for olefin and alkyne metathesis
    Benedikter, Mathis J.
    Ziegler, Felix
    Groos, Jonas
    Hauser, Philipp M.
    Schowner, Roman
    Buchmeiser, Michael R.
    COORDINATION CHEMISTRY REVIEWS, 2020, 415
12345