Free energy relationships in electrochemistry: a history that started in 1935

被引：55
作者：
Appleby, Anthony John [2 ]
Heraclito Zagal, Jose [1 ]
机构：
[1] Univ Santiago Chile, Fac Quim & Biol, Dept Quim Mat, Santiago 9170022, Chile
[2] Texas A&M Univ, Ctr Electrochem Syst & Hydrogen Res 3402, College Stn, TX 77843 USA
来源：
JOURNAL OF SOLID STATE ELECTROCHEMISTRY | 2011年 / 15卷 / 7-8期
关键词：
Tafel slopes; Butler-Volmer; Bronsted slopes; Marcus; Hush; Levich-Dogonadze; Volcano correlations; ELECTRON-TRANSFER REACTIONS; OXYGEN REDUCTION; BOND-BREAKING; ELECTROCATALYTIC ACTIVITY; HYDROGEN EVOLUTION; OUTER-SPHERE; ELECTROREDUCTIVE ALKYLATION; METAL PHTHALOCYANINES; ELEMENTARY PROCESSES; EXCHANGE CURRENT;
D O I：
10.1007/s10008-011-1394-8
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
This article is a historical overview of free energy relationships in electrochemistry with the purpose of giving the reader an integrated view on how these correlations are interconnected in various aspects starting with free energy correlations for outer-sphere and inner-sphere processes, Tafel correlations, the Butler-Volmer equation, and electron transfer theories. The citation of the literature is far from complete and is aimed to stimulate the reader to further reading.
引用
收藏
页码：1811 / 1832
页数：22
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