Synthesis and self-assembly of polythiophene-based rod-coil and coil-rod-coil block copolymers

被引：40
|
作者：
de Cuendias, A [1 ]
Le Hellaye, M [1 ]
Lecommandoux, B [1 ]
Cloutet, E [1 ]
Cramail, H [1 ]
机构：
[1] Univ Bordeaux 1, ENCPB, Lab Chim Polymeres Organ, CNRS UMR 5629, F-33607 Pessac, France
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2005年 / 15卷 / 32期
关键词：
D O I：
10.1039/b508490c
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Block copolymers constituted of flexible poly(n-butyl acrylate) or poly(tert-butyl acrylate) and rigid poly(3-hexylthiophene) segments have been synthesized by atom transfer radical polymerization and by oxidative polymerization accordingly. Two synthetic routes were followed to obtain rod-coil or coil rod-coil block copolymers. The self-assembly of the copolymers in solution in a selective solvent of the flexible block was studied by means of static and dynamic light scattering.
引用
收藏
页码：3264 / 3267
页数：4
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