Synthesis and self-assembly of polythiophene-based rod-coil and coil-rod-coil block copolymers

被引：40

作者：

de Cuendias, A ^{[1
]}

Le Hellaye, M ^{[1
]}

Lecommandoux, B ^{[1
]}

Cloutet, E ^{[1
]}

Cramail, H ^{[1
]}

机构：

[1] Univ Bordeaux 1, ENCPB, Lab Chim Polymeres Organ, CNRS UMR 5629, F-33607 Pessac, France

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2005年 / 15卷 / 32期

关键词：

D O I：

10.1039/b508490c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Block copolymers constituted of flexible poly(n-butyl acrylate) or poly(tert-butyl acrylate) and rigid poly(3-hexylthiophene) segments have been synthesized by atom transfer radical polymerization and by oxidative polymerization accordingly. Two synthetic routes were followed to obtain rod-coil or coil rod-coil block copolymers. The self-assembly of the copolymers in solution in a selective solvent of the flexible block was studied by means of static and dynamic light scattering.

引用

页码：3264 / 3267

页数：4

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