Highly dispersed heterogeneous palladium catalysts by the introduction of plant tannin into porous Al2O3 supports

被引:10
作者
Huang, Xin [1 ,2 ]
Mao, Hui [1 ]
Liao, Xuepin [1 ]
Shi, Bi [2 ]
机构
[1] Sichuan Univ, Dept Biomass Chem & Engn, Chengdu 610065, Peoples R China
[2] Sichuan Univ, Natl Engn Lab Clean Technol Leather Mfg, Chengdu 610065, Peoples R China
基金
中国国家自然科学基金;
关键词
Plant tannin; Pd catalyst; Dispersion; Activity; Catalytic hydrogenation; SURFACE; HYDROGENATION; SILICA;
D O I
10.1016/j.catcom.2011.03.008
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new strategy was provided by the introduction of plant tannins in porous Al2O3 to solve the problems of thermal migration of Pd during catalyst preparation, which ensured the preparation of heterogeneous Pd catalysts with well dispersion and superior activity. Compared with the conventional Pd-Al2O3 catalyst, the as-prepared heterogeneous Pd catalyst exhibited considerably improved Pd dispersion, which was highly active for the catalytic hydrogenation of olefins. Crown Copyright (C) 2011 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:1000 / 1004
页数:5
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