Template induced structural isomerism and enhancement of porosity in manganese(II) based metal-organic frameworks (Mn-MOFs)

被引：40
|
作者：
Panda, Tamas [1 ]
Pachfule, Pradip [1 ]
Banerjee, Rahul [1 ]
机构：
[1] Natl Chem Lab, Phys Mat Chem Div, Pune 411008, Maharashtra, India
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 27期
关键词：
COORDINATION POLYMERS; CATENATION ISOMERISM; SELECTIVE SORPTION; BUILDING-BLOCKS; GAS MOLECULES; HYDROGEN; CRYSTAL; DESIGN; LIGANDS; STORAGE;
D O I：
10.1039/c1cc12278a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three new metal-organic framework isomers have been synthesized by using the organic linker 5-triazole isophthalic acid and Mn(NO3)(2)center dot xH(2)O. Structural conversions from non-porous to porous MOFs due to the template effect have been observed. The cross-sectional pore apertures of the resulting Mn-MOFs are comparable to the molecular dimensions of the template (pyrazine and 4,40-bipyridine). The periodic increased porosity in Mn-MOFs depending on the size of the template used has been further confirmed by the CO2 adsorption isotherms.
引用
收藏
页码：7674 / 7676
页数：3
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