Ligand-Free Reusable Palladium-Catalyzed Heck-Type Coupling Reactions of Hypervalent Iodine Reagents under Mild Conditions

被引：33

作者：

Qu, Xiaoming ^{[1
]}

Sun, Peng ^{[1
]}

Li, Tingyi ^{[1
]}

Mao, Jincheng ^{[1
]}

机构：

[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2011年 / 353卷 / 07期

关键词：

aryl halides; coupling reactions; hypervalent iodine reagents; olefins; palladium catalysis; ELECTRON-RICH OLEFINS; REGIOSELECTIVE ARYLATION; EFFICIENT SYNTHESIS; ARYLBORONIC ACIDS; ARYL CHLORIDES; CHEMISTRY; PHOSPHINE; BROMIDES; NANOPARTICLES; ALKALOIDS;

D O I：

10.1002/adsc.201100008

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Highly effective palladium-catalyzed Heck-type couplings of hypervalent iodine reagents are reported for the first time. It is noteworthy that such reactions could be carried out in the absence of ligand at 40 degrees C and the catalytic system could be easily reused for five times.

引用

页码：1061 / 1066

页数：6

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