Main-group element compounds derived from the (1R,2R)-N,N′-bis(2-pyridylmethylene)cyclohexane-1,2-diamine (BPID) ligand

被引：4

作者：

Vasudevan, Kalyan V. ^{[1
]}

Scott, Brian L. ^{[2
]}

Gordon, John C. ^{[1
]}

机构：

[1] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA

[2] Los Alamos Natl Lab, Mat Phys & Applicat Div, Los Alamos, NM USA

来源：

MAIN GROUP CHEMISTRY | 2012年 / 11卷 / 01期

关键词：

Schiff-base; salt; BPID; main-group; SCHIFF-BASE LIGANDS; COORDINATION POLYMERS; COMPLEXES;

D O I：

10.3233/MGC-2012-0060

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the (1R,2R)-N,N'-Bis(2-pyridylmethylene)cyclohexane-1,2-diamine (BPID) ligand with 2 equivalents of GeCl2 center dot(dioxane) produced an unexpected germanium salt (1) while the reaction with two equivalents of TeBr4 resulted in a novel doubly-charged Te salt (2). These compounds represent the first main group complexes of the BPID ligand and demonstrate the unique reactivity of this versatile ligand class. Both compounds were characterized via single. crystal X-ray diffraction and elemental analysis, while compound 1 was further characterized by multinuclear NMR spectroscopy.

引用

页码：45 / 52

页数：8

共 27 条

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