Brightly Tricolored Mechanochromic Luminescence from a Single-Luminophore Liquid Crystal: Reversible Writing and Erasing of Images

被引:304
作者
Sagara, Yoshimitsu [1 ]
Kato, Takashi [1 ]
机构
[1] Univ Tokyo, Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan
基金
日本学术振兴会;
关键词
liquid crystals; luminescence; materials science; phase transitions; supramolecular chemistry; CYANO-SUBSTITUTED DIPHENYLBUTADIENES; PHOTOLUMINESCENT POLYMER BLENDS; SOLID-STATE FLUORESCENCE; INDUCED PHASE-TRANSITION; FOLIC-ACID DERIVATIVES; INDUCED COLOR CHANGES; MOLECULAR PACKING; ENERGY-TRANSFER; ASSEMBLIES; COMPLEXES;
D O I
10.1002/anie.201100914
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A glowing image: The photoluminescent colors reddish-orange, yellow, and green, are generated from a single liquid-crystalline mixture containing one luminophore (see picture). The colors are easily distinguished by the naked eye and can be reversibly written and erased. Moreover, these luminescent colors can be switched by mechanical and thermal stimuli. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:9128 / 9132
页数:5
相关论文
共 62 条
[1]   Luminescence color change of a platinum(II) complex solid upon mechanical grinding [J].
Abe, Taichi ;
Itakura, Toru ;
Ikeda, Noriaki ;
Shinozaki, Kazuteru .
DALTON TRANSACTIONS, 2009, (04) :711-715
[2]   Organogels as scaffolds for excitation energy transfer and light harvesting [J].
Ajayaghosh, Ayyappanpillai ;
Praveen, Vakayil K. ;
Vijayakumar, Chakkooth .
CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :109-122
[3]  
[Anonymous], ANGEW CHEM
[4]  
[Anonymous], 2008, ANGEW CHEM
[5]  
[Anonymous], 2008, ANGEW CHEM, DOI DOI 10.1002/ANGE.200803975
[6]  
[Anonymous], 2004, ANGEW CHEM
[7]  
[Anonymous], 2009, ANGEW CHEM
[8]   Dynamic Crystals: Visually Detected Mechanochemical Changes in the Luminescence of Gold and Other Transition-Metal Complexes [J].
Balch, Alan L. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (15) :2641-2644
[9]   Design of thermotropic liquid crystals with micellar cubic mesophases: Amphiphilic N-(2,3-dihydroxypropyl)benzamides [J].
Borisch, K ;
Diele, S ;
Goring, P ;
Kresse, H ;
Tschierske, C .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (19) :2087-2089
[10]   Deformation-induced color changes in melt-processed photoluminescent polymer blends [J].
Crenshaw, BR ;
Weder, C .
CHEMISTRY OF MATERIALS, 2003, 15 (25) :4717-4724