Ring Opening of Naphthene Hydrocarbons under Conditions of Thermal and Microwave Heating

被引：0

作者：

Finashina, E. D. ^{[1
]}

Tarasov, A. L. ^{[1
]}

机构：

[1] Zelinsky Inst Organ Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2018年 / 92卷 / 12期

关键词：

ring opening of naphthene hydrocarbons; Ir-containing catalysts; microwave heating; CATALYSTS; DECALIN; PYROLYSIS; PHENOLS; SYSTEMS;

D O I：

10.1134/S0036024418120130

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A comparative study of the activity and selectivity of monometallic Ir-containing catalysts in ring opening reactions under conditions of thermal and microwave heating is performed using the example of cyclohexane. The hydrogenolysis of cyclohexane is shown to be possible with microwave activation. It is found that upon microwave heating, iridium-containing catalysts supported on titanium oxide and activated carbon allow 60% selectivity to be reached with respect to ring opening products at 30% conversion of the initial cyclohexane.

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页码：2408 / 2411

页数：4

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