Incorporation of Homochirality into a Zeolitic Imidazolate Framework Membrane for Efficient Chiral Separation

被引:178
作者
Chan, Jun Yong [1 ]
Zhang, Huacheng [1 ]
Nolvachai, Yada [2 ]
Hu, Yaoxin [1 ]
Zhu, Haijin [3 ]
Forsyth, Maria [3 ]
Gu, Qinfen [4 ]
Hoke, David E. [5 ]
Zhang, Xiwang [1 ]
Marriot, Philip J. [2 ]
Wang, Huanting [1 ]
机构
[1] Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia
[2] Monash Univ, Dept Chem, Australian Ctr Res Separat Sci, Clayton, Vic 3800, Australia
[3] Deakin Univ, Inst Frontier Mat, Geelong, Vic 3216, Australia
[4] Australian Synchrotron, 800 Blackburn Rd, Clayton, Vic 3168, Australia
[5] Monash Univ, Dept Biochem & Mol Biol, Clayton, Vic 3800, Australia
基金
澳大利亚研究理事会;
关键词
chiral resolution; chirality; homochiral; membrane separation; metal-organic frameworks; METAL-ORGANIC FRAMEWORKS; AMINO-ACIDS; ENANTIOSELECTIVE RECOGNITION; RESOLUTION; MOF; ENANTIOMERS; ADSORPTION; STRATEGIES; POROSITY; PLATFORM;
D O I
10.1002/anie.201810925
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Homochiral metal-organic frameworks (MOFs) have gained much attention because of their chiral properties and disposition for chiral separation. However, the fabrication of high-quality homochiral MOF membranes remains challenging because of the difficulty in controlling growth of MOF membranes with chiral functionalities. A homochiral zeolitic imidazolate framework-8 (ZIF-8) membrane is reported for efficient chiral separation. The membrane is synthesized by incorporating a natural amino acid, L-histidine (L-His), into the framework of ZIF-8. The homochiral L-His-ZIF-8 membrane exhibits a good selectivity for the R-enantiomer of 1-phenylethanol over the S-enantiomer, showing a high enantiomeric excess value up to 76%.
引用
收藏
页码:17130 / 17134
页数:5
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