High electrically conductive polyaniline/partially phosphorylated poly(vinyl alcohol) composite films via aqueous dispersions

被引：19
作者：
Chen, Fei
Liu, Peng [1 ]
机构：
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China
来源：
MACROMOLECULAR RESEARCH | 2011年 / 19卷 / 09期
关键词：
conductive polymer; composite films; casting; mechanical properties; OXIDATIVE POLYMERIZATION; SOLUBLE POLYANILINE; PARTICLES; STABILITY; TRANSPORT; POLYMERS;
D O I：
10.1007/s13233-011-0901-1
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A novel low-cost approach was developed for the preparation of high electrically conducting composite films with high comprehensive properties. The polyaniline (PAn)/partially phosphorylated poly(vinyl alcohol) (P-PVA) dispersions were synthesized by the chemical oxidative polymerization of aniline in aqueous acidic (1 M HCl) media containing the partially phosphorylated poly(vinyl alcohol) (P-PVA), which can be cast directly to form smooth and mechanically robust composite films. The electrical, thermal, and mechanical properties of the PAn/P-PVA composite films were affected by the feeding ratio of aniline in polymerization. The uniform composite films showed a higher degree of crystalline orientation and higher electrical conductivity than those of the PAn/PVA films prepared with the same feeding ratio of aniline.
引用
收藏
页码：883 / 890
页数：8
相关论文
共 43 条
[11]   The dc and ac conductivity of polyaniline-polyvinyl alcohol blends [J].
Dutta, P ;
Biswas, S ;
Ghosh, M ;
De, SK ;
Chatterjee, S .
SYNTHETIC METALS, 2001, 122 (02) :455-461
[12]  
FRANCO DR, 2004, J MEMBRANE SCI, V234, P139
[13]   Water soluble polyaniline and its blend films prepared by aqueous solution casting [J].
Geng, YH ;
Sun, ZC ;
Li, J ;
Jing, XB ;
Wang, XH ;
Wang, FS .
POLYMER, 1999, 40 (20) :5723-5727
[14]   Studies on stable aqueous polyaniline prepared with the use of polyacrylamide as the water soluble support polymer [J].
Ghosh, P ;
Chakrabarti, A ;
Siddhanta, SK .
EUROPEAN POLYMER JOURNAL, 1999, 35 (05) :803-813
[15]   Unsaturated modified poly(vinyl alcohol).: Crosslinking through double bonds [J].
Giménez, V ;
Reina, JA ;
Mantecón, A ;
Cádiz, V .
POLYMER, 1999, 40 (10) :2759-2767
[16]   ON THE MECHANISM OF OXIDATIVE POLYMERIZATION OF ANILINE [J].
GOSPODINOVA, N ;
TERLEMEZYAN, L ;
MOKREVA, P ;
KOSSEV, K .
POLYMER, 1993, 34 (11) :2434-2437
[17]   Conducting polymers prepared by oxidative polymerization: Polyaniline [J].
Gospodinova, N ;
Terlemezyan, L .
PROGRESS IN POLYMER SCIENCE, 1998, 23 (08) :1443-1484
[18]   A new route to polyaniline composites [J].
Gospodinova, N ;
Mokreva, P ;
Tsanov, T ;
Terlemezyan, L .
POLYMER, 1997, 38 (03) :743-746
[19]  
GURURAJ M, 2010, POLYMER, V51, P2000
[20]   Synthesis and characterization of novel conducting composites of polyaniline prepared in the presence of sodium dodecylsulfonate and several water soluble polymers [J].
Hino, Tetsuo ;
Namiki, Takumi ;
Kuramoto, Noriyuki .
SYNTHETIC METALS, 2006, 156 (21-24) :1327-1332
12345