Interfacial synthesis and characterization of camphor sulfonic acid doped poly(aniline-co-2,5-dimethoxyaniline)

被引:10
作者
Muslim, Arzugul [1 ]
Abdryim, Tursun [2 ]
Zhi, Su [1 ]
机构
[1] Xinjiang Normal Univ, Sch Chem & Chem Engn, Urumqi 830054, Peoples R China
[2] Xinjiang Univ, Sch Chem & Chem Engn, Urumqi 830046, Peoples R China
基金
中国国家自然科学基金;
关键词
FACILE SYNTHESIS; POLYANILINE; POLYMERIZATION; COPOLYMER;
D O I
10.1134/S0965545X11060010
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polyaniline doped with camphor sulfonic acid, poly(2,5-dimethoxyaniline) and their copolymers were synthesized by interfacial method. The FT-IR spectra, UV-Vis absorption spectra and X-ray diffraction patterns were used to characterize the molecular structures of the polymers. The morphology of the polymers was studied by using SEM and TEM. Voltammetric study was done to investigate the electrochemical behavior of these polymers. The results show that the polymers were in microscale with the different shapes such as rod, flake and sphere, respectively. All the homopolymers and copolymers had a poor crystallinity. The conductivity of the copolymers of aniline with 2,5-dimethoxyaniline decreased with increase of 2,5-dimethoxy-aniline molar content.
引用
收藏
页码:480 / 487
页数:8
相关论文
共 33 条
  • [1] Comparative studies of solid-state synthesized polyaniline doped with inorganic acids
    Abdiryim, T
    Xiao-Gang, Z
    Jamal, R
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2005, 90 (2-3) : 367 - 372
  • [2] ABDIRYIM T, 2003, CHIN J APPL CHEM, V20, P1099
  • [3] Electrochemical synthesis of highly electroactive polydiphenylamine/polybenzidine copolymer in aqueous solutions
    Bagheri, A
    Nateghi, MR
    Massoumi, A
    [J]. SYNTHETIC METALS, 1998, 97 (02) : 85 - 89
  • [4] Synthesis and electrical properties of polymer composites with polyaniline nanoparticles
    Cho, MS
    Park, SY
    Hwang, JY
    Choi, HJ
    [J]. MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2004, 24 (1-2): : 15 - 18
  • [5] Studies on the structure of the aggregated state of ring-substituted polyaniline
    Dai, LZ
    Xu, YT
    Gal, JY
    Wu, HH
    [J]. ACTA PHYSICO-CHIMICA SINICA, 2002, 18 (03) : 237 - 242
  • [6] Dai LZ, 2002, CHEM J CHINESE U, V23, P1404
  • [7] DAI LZ, 2001, CHIN J APPL CHEM, V18, P272
  • [8] Ghadimi F, 2002, IRAN POLYM J, V11, P159
  • [9] HUANG DX, 1999, ACTA POLYM SIN, V3, P359
  • [10] Polyaniline nanofibers: Facile synthesis and chemical sensors
    Huang, JX
    Virji, S
    Weiller, BH
    Kaner, RB
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (02) : 314 - 315