Synthesis and Crystal Structure of a Manganese Complex with 3-Methyl-4-(p-bromophenyl)-5-(2-pyridyl)-1,2,4-triazole

被引：0
作者：
Zhao Jian [1 ]
Lu Wei [1 ]
Chen Lang [1 ]
Shen Xuan [1 ]
Xu Yan [1 ]
Zhu Dun-Ru [1 ,2 ]
机构：
[1] Nanjing Univ Technol, Coll Chem & Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Peoples R China
[2] Jiangsu Key Lab Chem Low Dimens Mat, Huaian 223300, Jiangsu, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2011年 / 27卷 / 04期
关键词：
Mn(II) complex; crystal structure; 1,2,4-triazole; DINUCLEAR NICKEL(II) COMPLEX; X-RAY-STRUCTURE; MAGNETIC-PROPERTY; COORDINATION CHEMISTRY; COPPER(II) COMPOUNDS; METAL-COMPLEXES; SPIN-CROSSOVER; LIGANDS;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new manganese(II) complex, cis-[MnL2(NCS)(2)], (L=3-methyl-4-(p-bromophenyl)-5-(2-pyridyl)-1,2,4-triazole), was synthesized and characterized by X-ray crystallography, FTIR. and ESI-MS spectra. The complex crystallizes in monoclinic system with space group P2(1/n), a=1.648 0(2), b =0.907 07(13), c=2.191. 9(3) nm, beta=97.454(2)degrees. V=3.248 8(8) nm(3), Z=4 with final R=0.043 9. The manganese atom lies in a distorted octahedral environment with two NCS- ions in the cis positions. The ligand L coordinates via one triazole nitrogen and one pyridine nitrogen atom. CCDC: 790351.
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页码：743 / 746
页数：4
相关论文
共 22 条
[1]   MULTIPLY-CHARGED IONS OF RUTHENIUM(II), RHODIUM(III) AND COBALT(III) COMPLEXES IN ELECTROSPRAY-IONIZATION MASS-SPECTROMETRY [J].
ARAKAWA, R ;
MATSUO, T ;
ITO, H ;
KATAKUSE, I ;
NOZAKI, K ;
OHNO, T ;
HAGA, MA .
ORGANIC MASS SPECTROMETRY, 1994, 29 (06) :289-294
[2]   SYNTHESIS AND COORDINATION CHEMISTRY OF A NOVEL DINUCLEATING CHELATING TRIAZOLE LIGAND - THE CRYSTAL-STRUCTURE OF BIS-MU-[4-AMINO-3,5-BIS(PYRIDIN-2-YL)-1,2,4-TRIAZOLE-N',MU-N1,MU-N2,N'']-BIS[AQUACHLORONICKEL(II)] DICHLORIDE TETRAHYDRATE [J].
KEIJ, FS ;
DEGRAAFF, RAG ;
HAASNOOT, JG ;
REEDIJK, J .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (10) :2093-2097
[3]   Spin crossover in iron(II) complexes of 3,5-di(2-pyridyl)-1,2,4-triazoles and 3,5-di(2-pyridyl)-1,2,4-triazolates [J].
Kitchen, Jonathan A. ;
Brooker, Sally .
COORDINATION CHEMISTRY REVIEWS, 2008, 252 (18-20) :2072-2092
[4]   First complexes of a 4-alkyl-3,5-di(2-pyridyl)-4H-1,2,4-triazole:: Synthesis, X-ray crystal structures and magnetic properties of dinuclear cobalt(II), nickel(II) and copper(II) complexes of 4-isobutyl-3,5-di(2-pyridyl)-4H-1,2,4-triazole [J].
Klingele, MH ;
Boyd, PDW ;
Moubaraki, B ;
Murray, KS ;
Brooker, S .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (05) :910-918
[5]   Synthesis and some first-row transition-metal complexes of the 1,2,4-triazole-based bis(terdentate) ligands TsPMAT and PMAT [J].
Klingele, MH ;
Moubaraki, B ;
Murray, KS ;
Brooker, S .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (23) :6962-6973
[6]   The coordination chemistry of 4-substituted 3,5-di(2-pyridyl)-4H-1,2,4-triazoles and related ligands [J].
Klingele, MH ;
Brooker, S .
COORDINATION CHEMISTRY REVIEWS, 2003, 241 (1-2) :119-132
[7]   MAGNETIC AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS WITH ALKYL-DISUBSTITUTED TRIAZOLES - X-RAY STRUCTURE OF BIS[MU-4-AMINO-3,5-BIS(AMINOMETHYL)-1,2,4-TRIAZOLE-N',N1,N2,N'']BIS[AQUABROMOCOPPER(II)] DIBROMIDE-2-WATER METHANOL [J].
KOOMENVANOUDENNIEL, WME ;
DEGRAAFF, RAG ;
HAASNOOT, JG ;
PRINS, R ;
REEDIJK, J .
INORGANIC CHEMISTRY, 1989, 28 (06) :1128-1133
[8]   Syntheses and crystal structures of two novel Cu(II) and Co(II) complexes with 3-methyl-4-(p-bromophenyl)-5-(2-pyridyl)-1,2,4-triazole [J].
Lu, Wei ;
Zhu, Dun-Ru ;
Xu, Yan ;
Cheng, Hui-Min ;
Zhao, Jian ;
Shen, Xuan .
STRUCTURAL CHEMISTRY, 2010, 21 (01) :237-244
[9]   Cooperative spin crossover and order-disorder phenomena in a mononuclear compound [Fe(DAPP)(abpt)](ClO4)2 [DAPP = [bis(3-aminopropyl)(2-pyridylmethyl)amine], abpt=4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole] [J].
Matouzenko, GS ;
Bousseksou, A ;
Borshch, SA ;
Perrin, M ;
Zein, S ;
Salmon, L ;
Molnar, G ;
Lecocq, S .
INORGANIC CHEMISTRY, 2004, 43 (01) :227-236
[10]   MAGNETIC-PROPERTIES OF DIMERIC DISUBSTITUTED-TRIAZOLE COPPER(II) COMPOUNDS - X-RAY STRUCTURE OF BIS[MU-3,5-BIS(PYRIDIN-2-YL)-1,2,4-TRIAZOLATO-N',N1,N2,N'']-BIS[AQUA(TRIFLUOROMETHANESULFONATO-O)COPPER(II)] [J].
PRINS, R ;
BIRKER, PJMWL ;
HAASNOOT, JG ;
VERSCHOOR, GC ;
REEDIJK, J .
INORGANIC CHEMISTRY, 1985, 24 (24) :4128-4133
123