Biocidal poly (vinyl alcohol) films incorporated with N-halamine siloxane

被引:16
|
作者
Li, Rong [1 ]
Sheng, Junfeng [1 ]
Cheng, Xiaoli [1 ]
Li, Jing [1 ]
Ren, Xuehong [1 ]
Huang, Tung-Shi [2 ]
机构
[1] Jiangnan Univ, Coll Text & Clothing, Minist Educ, Key Lab Ecotext, Wuxi 214122, Jiangsu, Peoples R China
[2] Auburn Univ, Dept Poultry Sci, Auburn, AL 36849 USA
基金
中国国家自然科学基金;
关键词
N-halamine; Antibacterial; PVA; Cross linked film; ANTIBACTERIAL ACTIVITY; BLEND FILMS; NANOPARTICLES; CHITOSAN; COATINGS; COTTON; NANOFIBERS; MEMBRANES; MONOMER; FIBERS;
D O I
10.1016/j.coco.2018.07.005
中图分类号
TB33 [复合材料];
学科分类号
摘要
An N-halamine siloxane precursor gamma-(beta-hydroxyl-gamma-5,5-dimethylhydantoin)aminopropyltrithoxysilane (abbreviated as GHAPA) was synthesized in this study. GHAPA was mixed with PVA solution to prepare PVA/GHAPA cross linked film with an antimicrobial function. The obtained PVA/GHAPA cross linked film was characterized by TGA, DSC and XRD. Upon dilute household bleach treatment, the chlorinated PVA/GHAPA cross linked film could inactivate Staphylococcus aureus and Escherichia coll. O157:H7 completely with concentrations of 4.57 x 10(7) cfu and 2.70 x 10(7) cfu within 5 and 10 min, respectively, and 99.9995% of Escherichia coll. O157:H7 could be inactivated within 5 min. The antimicrobial results showed that the chlorinated films substantially outperformed the unchlorinated control samples. The biocidal films may serve as potential materials for food packaging and biomedical applications.
引用
收藏
页码:89 / 92
页数:4
相关论文
共 50 条
  • [21] Biocidal Activity of N-Halamine Methylenebisacrylamide Grafted Cotton
    Li, Xiaolin
    Liu, Ying
    Liu, Yin
    Du, Jinmei
    Li, Rong
    Ren, Xuehong
    Huang, Tung-Shi
    JOURNAL OF ENGINEERED FIBERS AND FABRICS, 2015, 10 (02): : 147 - 154
  • [22] Biocidal hydantoinylsiloxane polymers. IV. N-halamine siloxane- functionalized silica gel
    Liang, J.
    Owens, J.R.
    Huang, T.S.
    Worley, S.D.
    Journal of Applied Polymer Science, 2006, 101 (05): : 3448 - 3454
  • [23] Synthesis and characterization of biocidal poly(oxyethylene)s having N-halamine side groups
    Choi, Kwonyong
    Nam, Moon-Ja
    Kim, Jee Yeon
    Yoon, Jeyong
    Lee, Jong-Chan
    MACROMOLECULAR RESEARCH, 2011, 19 (12) : 1227 - 1232
  • [24] Poly(vinyl alcohol) Blend Film with m-Aramid as an N-halamine Precursor for Antimicrobial Activity
    Lee, Jaewoong
    Whang, Hyun Suk
    JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 122 (04) : 2345 - 2350
  • [25] Biocidal hydantoinylsiloxane polymers.: IV.: N-halamine siloxane-functionalized silica gel
    Liang, J.
    Owens, J. R.
    Huang, T. S.
    Worley, S. D.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 101 (05) : 3448 - 3454
  • [26] Antimicrobial properties of novel n-halamine siloxane coatings
    Williams, JF
    Suess, J
    Santiago, J
    Chen, Y
    Wang, J
    Wu, R
    Worley, SD
    SURFACE COATINGS INTERNATIONAL PART B-COATINGS TRANSACTIONS, 2005, 88 (01) : 35 - 39
  • [27] Synthesis and characterization of biocidal poly(oxyethylene)s having N-halamine side groups
    Kwonyong Choi
    Moon-Ja Nam
    Jee Yeon Kim
    Jeyong Yoon
    Jong-Chan Lee
    Macromolecular Research, 2011, 19 : 1227 - 1232
  • [28] A novel N-halamine monomer for preparing biocidal polyurethane coatings
    Worley, SD
    Li, F
    Wu, R
    Kim, J
    Wei, CI
    Williams, JF
    Owens, JR
    Wander, JD
    Bargmeyer, AM
    Shirtliff, ME
    SURFACE COATINGS INTERNATIONAL PART B-COATINGS TRANSACTIONS, 2003, 86 (04) : 273 - 277
  • [29] Mechanism of decomposition of antimicrobial N-halamine siloxane coatings
    Kocer, Hasan B.
    Akdag, Akin
    Worley, S. D.
    Broughton, R. M.
    Wu, Yonnie
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
  • [30] N-halamine Modified Polyester Fabrics: Preparation and Biocidal Functions
    Ma, Kaikai
    Jiang, Zhiming
    Li, Lin
    Liu, Ying
    Ren, Xuehong
    Huang, Tung-Shi
    FIBERS AND POLYMERS, 2014, 15 (11) : 2340 - 2344