Biocidal poly (vinyl alcohol) films incorporated with N-halamine siloxane

被引:16
|
作者
Li, Rong [1 ]
Sheng, Junfeng [1 ]
Cheng, Xiaoli [1 ]
Li, Jing [1 ]
Ren, Xuehong [1 ]
Huang, Tung-Shi [2 ]
机构
[1] Jiangnan Univ, Coll Text & Clothing, Minist Educ, Key Lab Ecotext, Wuxi 214122, Jiangsu, Peoples R China
[2] Auburn Univ, Dept Poultry Sci, Auburn, AL 36849 USA
基金
中国国家自然科学基金;
关键词
N-halamine; Antibacterial; PVA; Cross linked film; ANTIBACTERIAL ACTIVITY; BLEND FILMS; NANOPARTICLES; CHITOSAN; COATINGS; COTTON; NANOFIBERS; MEMBRANES; MONOMER; FIBERS;
D O I
10.1016/j.coco.2018.07.005
中图分类号
TB33 [复合材料];
学科分类号
摘要
An N-halamine siloxane precursor gamma-(beta-hydroxyl-gamma-5,5-dimethylhydantoin)aminopropyltrithoxysilane (abbreviated as GHAPA) was synthesized in this study. GHAPA was mixed with PVA solution to prepare PVA/GHAPA cross linked film with an antimicrobial function. The obtained PVA/GHAPA cross linked film was characterized by TGA, DSC and XRD. Upon dilute household bleach treatment, the chlorinated PVA/GHAPA cross linked film could inactivate Staphylococcus aureus and Escherichia coll. O157:H7 completely with concentrations of 4.57 x 10(7) cfu and 2.70 x 10(7) cfu within 5 and 10 min, respectively, and 99.9995% of Escherichia coll. O157:H7 could be inactivated within 5 min. The antimicrobial results showed that the chlorinated films substantially outperformed the unchlorinated control samples. The biocidal films may serve as potential materials for food packaging and biomedical applications.
引用
收藏
页码:89 / 92
页数:4
相关论文
共 50 条
  • [1] N-halamine/quat siloxane copolymers for use in biocidal coatings
    Liang, J
    Chen, Y
    Barnes, K
    Wu, R
    Worley, SD
    Huang, TS
    BIOMATERIALS, 2006, 27 (11) : 2495 - 2501
  • [2] Acyclic N-Halamine Polymeric Biocidal Films
    Ren, Xuehong
    Zhu, Changyun
    Kou, Lei
    Worley, S. D.
    Kocer, Hasan B.
    Broughton, R. M.
    Huang, T. S.
    JOURNAL OF BIOACTIVE AND COMPATIBLE POLYMERS, 2010, 25 (04) : 392 - 405
  • [3] Novel biocidal N-halamine plastic based on poly(vinyl chloride): Preparation and characteristics
    Chylinska, Marta
    Kaczmarek, Halina
    Burkowska-But, Aleksandra
    Walczak, Maciej
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2015, 28 : 124 - 130
  • [4] Novel N-halamine siloxane monomers and polymers for preparing biocidal coatings
    Worley, SD
    Chen, Y
    Wang, JW
    Wu, R
    SURFACE COATINGS INTERNATIONAL PART B-COATINGS TRANSACTIONS, 2005, 88 (02) : 93 - 99
  • [5] N-halamine biocidal coatings
    Liang, J.
    Wu, R.
    Wang, J. -W.
    Barnes, K.
    Worley, S. D.
    Cho, U.
    Lee, J.
    Broughton, R. M.
    Huang, T. -S.
    JOURNAL OF INDUSTRIAL MICROBIOLOGY & BIOTECHNOLOGY, 2007, 34 (02) : 157 - 163
  • [6] Antimicrobial N-Halamine incorporated Poly(Vinyl alcohol-co-ethylene) films for reducing cross-contamination of fresh produce
    Yi, Jiyoon
    Huang, Kang
    Ma, Yue
    Sun, Gang
    Young, Glenn M.
    Nitin, Nitin
    FOOD CONTROL, 2021, 124
  • [7] N-halamine copolymers for biocidal coatings
    Cerkez, Idris
    Kocer, Hasan B.
    Worley, S. D.
    Broughton, R. M.
    Huang, T. S.
    REACTIVE & FUNCTIONAL POLYMERS, 2012, 72 (10): : 673 - 679
  • [8] New N-halamine biocidal polymers
    Eknoian, MW
    Worley, SD
    JOURNAL OF BIOACTIVE AND COMPATIBLE POLYMERS, 1998, 13 (04) : 303 - 314
  • [9] New N-halamine biocidal polymers
    Department of Chemistry, Auburn University, Auburn, AL 36849, United States
    J. Bioact. Compat. Polym., 4 (303-314):
  • [10] Electro-spinning Antimicrobial N-halamine Modified Poly(vinyl alcohol)Nanofibers
    姜潜远
    任学宏
    黄东时
    JournalofDonghuaUniversity(EnglishEdition), 2014, 31 (01) : 44 - 49