Removal of Cu2+ from Water Using Liquid-Liquid Microchannel Extraction

被引:13
作者
Liu, Hui [1 ]
Dai, Shuang [1 ]
Li, Jun [1 ]
Ma, Rui [1 ]
Cao, Yan [1 ]
Wang, Gang [2 ]
Komarneni, Sridhar [3 ,4 ]
Luo, Jianhong [1 ]
机构
[1] Sichuan Univ, Dept Chem Engn, Chengdu 610065, Peoples R China
[2] Shandong Univ Sci & Technol, Mine Disaster Prevent & Control Minist, State Key Lab Breeding Base, Qingdao 266590, Peoples R China
[3] Penn State Univ, Dept Ecosyst Sci & Management, University Pk, PA 16802 USA
[4] Penn State Univ, Mat Res Lab, Mat Res Inst, University Pk, PA 16802 USA
关键词
Cu2+; Extraction efficiency; Liquid-liquid extraction; Mass transfer; Microchannel; MASS-TRANSFER; SOLVENT-EXTRACTION; CHANNEL REACTOR; SEPARATION; MEMBRANE; IONS; ACID; MICROEXTRACTION; SPLIT;
D O I
10.1002/ceat.201900168
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The very good extraction selectivity of Cu2+ from water was demonstrated with a new microchannel equipment, by employing di-(2-ethylhexyl)phosphoric acid (D2EHPA) as an extractant and kerosene as a solvent. The effects of different experimental parameters on the extraction efficiency E, the volumetric mass transfer coefficient K(L)a, and the entrainment were experimentally investigated. The results showed that the extraction efficiency increased with increasing temperature, extractant concentration, phase ratio (organic/aqueous), and pH. The total flow rate, phase ratio, and pH were found to have a great effect on the mass transfer, whereas the temperature and the extractant concentration showed little effect.
引用
收藏
页码:974 / 982
页数:9
相关论文
共 48 条
[21]  
Ling G. L., 2005, J NE U, V16, P303
[22]  
[马前 Ma Qian], 2007, [环境工程学报, Chinese Journal of Environmental Engineering], V1, P10
[23]   Electrochemical deposition of Cu and Ta from pyrrolidinium based ionic liquid [J].
Mais, Laura ;
Mascia, Michele ;
Vacca, Annalisa ;
Palmas, Simonetta ;
Delogu, Francesco .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2015, 45 (07) :735-744
[24]   Relationship between Rheological Properties and One-Step W/O/W Multiple Emulsion Formation [J].
Morais, Jacqueline M. ;
Rocha-Filho, Pedro A. ;
Burgess, Diane J. .
LANGMUIR, 2010, 26 (23) :17874-17881
[25]  
Nabel A. N., 2015, J IND ENG CHEM, V21, P526, DOI [10.1016/j.jiec.2014.03.015, DOI 10.1016/J.JIEC.2014.03.015]
[26]   An innovative membrane method for the separation of chromium ions from solutions containing obstructive copper ions [J].
Pazouki, Mahshad ;
Moheb, Ahmad .
DESALINATION, 2011, 274 (1-3) :246-254
[27]  
Plouffe P., 2014, CHEM ENG J, DOI [http://dx.doi.org/10.1016/j.cej.2014.10.072, DOI 10.1016/J.CEJ.2014.10.072]
[28]   Ionic liquid synthesis in a microstructured reactor for process intensification [J].
Renken, A. ;
Hessel, V. ;
Loeb, P. ;
Miszczuk, R. ;
Uerdingen, M. ;
Kiwi-Minsker, L. .
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2007, 46 (09) :840-845
[29]   An optimised split-and-recombine micro-mixer with uniform 'chaotic' mixing [J].
Schönfeld, F ;
Hessel, V ;
Hofmann, C .
LAB ON A CHIP, 2004, 4 (01) :65-69
[30]  
SEN N, 2013, BARC NEWSL, V334, P20