Tunable Aryl Imidazolium Recyclable Ionic Liquid with Dual BrOnsted-Lewis Acid as Green Catalyst for Friedel-Crafts Acylation and Thioesterification

被引：14

作者：

Lin, Yi-Jyun ^{[1
]}

Wu, Yao-Peng ^{[1
]}

Thul, Mayur ^{[1
]}

Hung, Ming-Wei ^{[1
]}

Chou, Shih-Huan ^{[2
]}

Chen, Wen-Tin ^{[3
]}

Lin, Wesley ^{[4
]}

Lin, Michelle ^{[4
]}

Reddy, Daggula Mallikarjuna ^{[1
]}

Wu, Hsin-Ru ^{[5
]}

Ho, Wen-Yueh ^{[6
,7
]}

Luo, Shun-Yuan ^{[1
]}

机构：

[1] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan

[2] Taipei Amer Sch, Dept Chem, Taipei 111, Taiwan

[3] Taichung Municipal Chungming Senior High Sch, Dept Chem, Taichung 403, Taiwan

[4] Morrison Acad, Dept Chem, Taichung 406, Taiwan

[5] Natl Tsing Hua Univ, MOST, Instrumentat Ctr, Hsinchu 30013, Taiwan

[6] Chia Nan Univ Pharm & Sci, Dept Cosmet Sci, Tainan 717, Taiwan

[7] Chia Nan Univ Pharm & Sci, Inst Cosmet Sci, Tainan 717, Taiwan

来源：

MOLECULES | 2020年 / 25卷 / 02期

关键词：

ionic liquids; Friedel-Crafts acylation; thioesterification; recyclable; INTERMOLECULAR RADICAL REACTION; THIOESTERS; ALDEHYDES; EFFICIENT; SUPERACIDS; REDUCTION; THIOLS;

D O I：

10.3390/molecules25020352

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Unique tunable aryl imidazolium ionic liquids successfully catalyzed Friedel-Crafts acylation and thioesterification in sealed tubes. These reactions can form a C-C bond and a C-S bond with high atom economy. Ionic liquids exhibited high activity and catalyzed essential reactions with good to excellent yields while retaining their catalytic activities for recycling.

引用

页数：15

共 29 条

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APPLIED SCIENCES-BASEL, 2019, 9 (22):
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