Enantioselective chromatographic resolution and one-pot synthesis of enantiomerically pure sulfoxides over a homochiral Zn-organic framework

被引：247

作者：

Nuzhdin, Alexey L.

Dybtsev, Danil N.

Bryliakov, Konstantin P.

Talsi, Evgenii P.

Fedin, Vladimir P.

机构：

[1] Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia

[2] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 43期

关键词：

D O I：

10.1021/ja076276p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(R )- and (S )- enantiomers of alkyl aryl sulfoxides can be obtained by chromatographic resolution of the racemic mixtures of the sulfoxides on a microporous homochiral Zn-organic polymer or by simultaneous catalytic oxidation of the corresponding sulfides with H2O2 and enantioselective chromatographic resolution of the resulting sulfoxides in a one-pot process.

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页码：12958 / +

页数：3

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